Vibrational relaxation of guest and host in mixed molecular crystals

Jeffrey R. Hill; Eric L. Chronister; Ta Chau Chang; Hackjin Kim; Jay C. Postlewaite; Dana D. Dlott

doi:10.1063/1.454019

Vibrational relaxation of guest and host in mixed molecular crystals

Jeffrey R. Hill, Eric L. Chronister, Ta Chau Chang, Hackjin Kim, Jay C. Postlewaite, Dana D. Dlott

Research output: Contribution to journal › Article › peer-review

Abstract

Vibrational relaxation (VR) of dilute impurity molecules (naphthalene, anthracene) in crystalline host matrices (durene, naphthalene) is studied with the ps photon echo technique. The results obtained by echoes on vibrations in the electronically excited state are compared to previous ps time delayed coherent Raman studies of ground state vibrations of the pure host matrix. The relaxation channels for guest and host, and the effects of molecular and crystal structure on VR rates are determined.

Original language	English (US)
Pages (from-to)	2361-2371
Number of pages	11
Journal	The Journal of Chemical Physics
Volume	88
Issue number	4
DOIs	https://doi.org/10.1063/1.454019
State	Published - 1988

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.454019

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abstract = "Vibrational relaxation (VR) of dilute impurity molecules (naphthalene, anthracene) in crystalline host matrices (durene, naphthalene) is studied with the ps photon echo technique. The results obtained by echoes on vibrations in the electronically excited state are compared to previous ps time delayed coherent Raman studies of ground state vibrations of the pure host matrix. The relaxation channels for guest and host, and the effects of molecular and crystal structure on VR rates are determined.",

author = "Hill, {Jeffrey R.} and Chronister, {Eric L.} and Chang, {Ta Chau} and Hackjin Kim and Postlewaite, {Jay C.} and Dlott, {Dana D.}",

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language = "English (US)",

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T1 - Vibrational relaxation of guest and host in mixed molecular crystals

AU - Hill, Jeffrey R.

AU - Chronister, Eric L.

AU - Chang, Ta Chau

AU - Kim, Hackjin

AU - Postlewaite, Jay C.

AU - Dlott, Dana D.

PY - 1988

Y1 - 1988

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AB - Vibrational relaxation (VR) of dilute impurity molecules (naphthalene, anthracene) in crystalline host matrices (durene, naphthalene) is studied with the ps photon echo technique. The results obtained by echoes on vibrations in the electronically excited state are compared to previous ps time delayed coherent Raman studies of ground state vibrations of the pure host matrix. The relaxation channels for guest and host, and the effects of molecular and crystal structure on VR rates are determined.

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JF - The Journal of Chemical Physics

IS - 4

ER -

Vibrational relaxation of guest and host in mixed molecular crystals

Abstract

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