Vibrational energy transfer across a reverse micelle surfactant layer

John C. Deàk, Yoonsoo Pang, Timothy D. Sechler, Zhaohui Wang, Dana D. Dlott

Research output: Contribution to journalArticle

Abstract

In a Suspension of reverse micelles, in which the surfactant sodium dioctyl sulfosuccinate (AOT) separates a water nanodroplet from a bulk nonpolar CCl4 phase, ultrafast vibrational spectroscopy was used to study vibrational energy transfer from the nanodroplet through the AOT interfacial monolayer to the surrounding CCl4. Most of the vibrational energy from the nanodroplet was transferred to the polar AOT head group within 1.8 picoseconds and then out to the CCl4 within 10 picoseconds. Vibrational energy pumped directly into the AOT tail resulted in a slower 20- to 40-picosecond transfer of energy to the CCl4.

Original languageEnglish (US)
Pages (from-to)473-476
Number of pages4
JournalScience
Volume306
Issue number5695
DOIs
StatePublished - Oct 15 2004

ASJC Scopus subject areas

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