Abstract
The lowest six vibrational hot bands of CF+ have been measured in a helium/C2F6 discharge by velocity modulation laser spectroscopy. A total of 56 transitions has been fitted to Dunham expansion for v = 0-7, yielding the parameters: ωe = 1792.6654(18) cm-1Be = 1.7204176(75) cm-1, Y20, = -13.22968(54) cm-1, and D0 = 62086(30) cm-1. The rotational temperature of CF+ in the plasma is near 650 K and the vibrational temperature is approximately 5200 K.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 165-169 |
| Number of pages | 5 |
| Journal | Chemical Physics Letters |
| Volume | 125 |
| Issue number | 2 |
| DOIs | |
| State | Published - Mar 28 1986 |
| Externally published | Yes |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Cite this
Gruebele, M., Polak, M., & Saykally, R. J. (1986). Velocity modulation laser spectroscopy of vibrationally excited CF+ determination of the molecular potential function. Chemical Physics Letters, 125(2), 165-169. https://doi.org/10.1016/0009-2614(86)85096-5