Using the plasmon linewidth to calculate the time and efficiency of electron transfer between gold nanorods and graphene

Anneli Hoggard, Lin Yung Wang, Lulu Ma, Ying Fang, Ge You, Jana Olson, Zheng Liu, Wei Shun Chang, Pulickel M. Ajayan, Stephan Link

Research output: Contribution to journalArticlepeer-review


We present a quantitative analysis of the electron transfer between single gold nanorods and monolayer graphene under no electrical bias. Using single-particle dark-field scattering and photoluminescence spectroscopy to access the homogeneous linewidth, we observe broadening of the surface plasmon resonance for gold nanorods on graphene compared to nanorods on a quartz substrate. Because of the absence of spectral plasmon shifts, dielectric interactions between the gold nanorods and graphene are not important and we instead assign the plasmon damping to charge transfer between plasmon-generated hot electrons and the graphene that acts as an efficient acceptor. Analysis of the plasmon linewidth yields an average electron transfer time of 160 ± 30 fs, which is otherwise difficult to measure directly in the time domain with single-particle sensitivity. In comparison to intrinsic hot electron decay and radiative relaxation, we furthermore calculate from the plasmon linewidth that charge transfer between the gold nanorods and the graphene support occurs with an efficiency of ∼10%. Our results are important for future applications of light harvesting with metal nanoparticle plasmons and efficient hot electron acceptors as well as for understanding hot electron transfer in plasmon-assisted chemical reactions.

Original languageEnglish (US)
Pages (from-to)11209-11217
Number of pages9
JournalACS Nano
Issue number12
StatePublished - Dec 23 2013
Externally publishedYes


  • graphene
  • hot electrons
  • one-photon photoluminescence
  • plasmon damping
  • plasmon linewidth
  • single-particle spectroscopy
  • surface plasmon resonance

ASJC Scopus subject areas

  • General Materials Science
  • General Engineering
  • General Physics and Astronomy


Dive into the research topics of 'Using the plasmon linewidth to calculate the time and efficiency of electron transfer between gold nanorods and graphene'. Together they form a unique fingerprint.

Cite this