Uranium-hydrogen interactions: Synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(iii)

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Abstract

The reaction of UCl4 with Na(H3BNMe 2BH3) in diethyl ether affords the uranium(iii) product U(H3BNMe2BH3)3, which has been crystallized in two different structural isomers depending on the crystallization solvent. Both forms are polymeric, but the nature of the bridging interaction is different in the two forms.

Original languageEnglish (US)
Pages (from-to)407-408
Number of pages2
JournalChemical Communications
Volume46
Issue number3
DOIs
StatePublished - 2010

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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