Unsupported d8–d8 interactions in cationic PdII and PtII complexes: Evidence for a significant metal–metal bonding character

Jia Luo; Julia R. Khusnutdinova; Nigam P. Rath; Liviu M. Mirica

doi:10.1039/c1cc15420f

Unsupported d⁸–d⁸ interactions in cationic Pd^II and Pt^II complexes: Evidence for a significant metal–metal bonding character

Jia Luo, Julia R. Khusnutdinova, Nigam P. Rath, Liviu M. Mirica

Research output: Contribution to journal › Article › peer-review

Abstract

Isostructural dinuclear Pd and Pt complexes that exhibit unique d⁸–d⁸ interactions between dicationic metal centers are reported. These metal–metal interactions are not supported by any bridging ligands and suggest a significant metal–metal bonding character for both Pd and Pt systems.

Original language	English (US)
Pages (from-to)	1532-1534
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	10
DOIs	https://doi.org/10.1039/c1cc15420f
State	Published - Jan 11 2012
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Online availability

10.1039/c1cc15420f

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Cite this

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title = "Unsupported d8–d8 interactions in cationic PdII and PtII complexes: Evidence for a significant metal–metal bonding character",

abstract = "Isostructural dinuclear Pd and Pt complexes that exhibit unique d8–d8 interactions between dicationic metal centers are reported. These metal–metal interactions are not supported by any bridging ligands and suggest a significant metal–metal bonding character for both Pd and Pt systems.",

author = "Jia Luo and Khusnutdinova, {Julia R.} and Rath, {Nigam P.} and Mirica, {Liviu M.}",

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journal = "Chemical Communications",

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AU - Luo, Jia

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AU - Rath, Nigam P.

AU - Mirica, Liviu M.

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AB - Isostructural dinuclear Pd and Pt complexes that exhibit unique d8–d8 interactions between dicationic metal centers are reported. These metal–metal interactions are not supported by any bridging ligands and suggest a significant metal–metal bonding character for both Pd and Pt systems.

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