U-series disequilibria in Kick'em Jenny submarine volcano lavas: A new view of time-scales of magmatism in convergent margins

We present data for U and its decay series nuclides ²³⁰Th, ²²⁶Ra, ²³¹Pa, and ²¹⁰Po for 14 lavas from Kick'em Jenny (KEJ) submarine volcano to constrain the time-scales and processes of magmatism in the Southern Lesser Antilles, the arc having the globally lowest plate convergence rate. Although these samples are thought to have been erupted in the last century, most have (²²⁶Ra)/(²¹⁰Po) within ±15% of unity. Ten out of 14 samples have significant ²²⁶Ra excesses over ²³⁰Th, with (²²⁶Ra)/(²³⁰Th) up to 2.97, while four samples are in ²²⁶Ra-²³⁰Th equilibrium within error. All KEJ samples have high (²³¹Pa)/(²³⁵U), ranging from 1.56 to 2.64 and high ²³⁸U excesses (up to 43%), providing a global end-member of high ²³⁸U and high ²³¹Pa excesses. Negative correlations between Sr, sensitive to plagioclase fractionation, and Ho/Sm, sensitive to amphibole fractionation, or K/Rb, sensitive to open system behavior, indicate that differentiation at KEJ lavas was dominated by amphibole fractionation and open-system assimilation. While (²³¹Pa)/(²³⁵U) does not correlate with differentiation indices such as Ho/Sm, (²³⁰Th)/(²³⁸U) shows a slight negative correlation, likely due to assimilation of materials with slightly higher (²³⁰Th)/(²³⁸U). Samples with ²²⁶Ra excess have higher Sr/Th and Ba/Th than those in ²²⁶Ra-²³⁰Th equilibrium, forming rough positive correlations of (²²⁶Ra)/(²³⁰Th) with Sr/Th and Ba/Th similar to those observed in many arc settings. We interpret these correlations to reflect a time-dependent magma differentiation process at shallow crustal levels and not the process of recent fluid addition at the slab-wedge interface. The high ²³¹Pa excesses require an in-growth melting process operating at low melting rates and small residual porosity; such a model will also produce significant ²³⁸U-²³⁰Th and ²²⁶Ra-²³⁰Th disequilibrium in erupted lavas, meaning that signatures of recent fluid addition from the slab are unlikely to be preserved in KEJ lavas. We instead propose that most of the ²³⁸U-²³⁰Th, ²²⁶Ra-²³⁰Th, and ²³⁵U-²³¹Pa disequilibria in erupted KEJ lavas reflect the in-growth melting process in the mantle wedge (reflecting variations in U/Th, daughter-parent ratios, fO₂, and thermal structure), followed by modification by magma differentiation at crustal depths. Such a conclusion reconciles the different temporal implications from different U-series parent-daughter pairs and relaxes the time constraint on mass transfer from slab to eruption occurring in less than a few thousand years imposed by models whereby ²²⁶Ra excess is derived from the slab.