Time-resolved x-ray photoelectron spectroscopy techniques for real-time studies of interfacial charge transfer dynamics

Andrey Shavorskiy; Amy Cordones; Josh Vura-Weis; Katrin Siefermann; Daniel Slaughter; Felix Sturm; Fabian Weise; Hendrik Bluhm; Matthew Strader; Hana Cho; Ming Fu Lin; Camila Bacellar; Champak Khurmi; Marcus Hertlein; Jinghua Guo; Tolek Tyliszczak; David Prendergast; Giacomo Coslovich; Joseph Robinson; Robert A. Kaindl; Robert W. Schoenlein; Ali Belkacem; Thorsten Weber; Daniel M. Neumark; Stephen R. Leone; Dennis Nordlund; Hirohito Ogasawara; Anders R. Nilsson; Oleg Krupin; Joshua J. Turner; William F. Schlotter; Michael R. Holmes; Philip A. Heimann; Marc Messerschmidt; Michael P. Minitti; Martin Beye; Sheraz Gul; Jin Z. Zhang; Nils Huse; Oliver Gessner

doi:10.1063/1.4802374

Time-resolved x-ray photoelectron spectroscopy techniques for real-time studies of interfacial charge transfer dynamics

Andrey Shavorskiy, Amy Cordones, Josh Vura-Weis, Katrin Siefermann, Daniel Slaughter, Felix Sturm, Fabian Weise, Hendrik Bluhm, Matthew Strader, Hana Cho, Ming Fu Lin, Camila Bacellar, Champak Khurmi, Marcus Hertlein, Jinghua Guo, Tolek Tyliszczak, David Prendergast, Giacomo Coslovich, Joseph Robinson, Robert A. KaindlRobert W. Schoenlein, Ali Belkacem, Thorsten Weber, Daniel M. Neumark, Stephen R. Leone, Dennis Nordlund, Hirohito Ogasawara, Anders R. Nilsson, Oleg Krupin, Joshua J. Turner, William F. Schlotter, Michael R. Holmes, Philip A. Heimann, Marc Messerschmidt, Michael P. Minitti, Martin Beye, Sheraz Gul, Jin Z. Zhang, Nils Huse, Oliver Gessner

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

X-ray based spectroscopy techniques are particularly well suited to gain access to local oxidation states and electronic dynamics in complex systems with atomic pinpoint accuracy. Traditionally, these techniques are applied in a quasi-static fashion that usually highlights the steady-state properties of a system rather than the fast dynamics that often define the system function on a molecular level. Novel x-ray spectroscopy techniques enabled by free electron lasers (FELs) and synchrotron based pump-probe schemes provide the opportunity to monitor intramolecular and interfacial charge transfer processes in real-time and with element and chemical specificity. Two complementary time-domain xray photoelectron spectroscopy techniques are presented that are applied at the Linac Coherent Light Source (LCLS) and the Advanced Light Source (ALS) to study charge transfer processes in N3 dye-sensitized ZnO semiconductor nanocrystals, which are at the heart of emerging light-harvesting technologies.

Original language	English (US)
Title of host publication	Application of Accelerators in Research and Industry - Twenty-Second International Conference
Pages	475-479
Number of pages	5
DOIs	https://doi.org/10.1063/1.4802374
State	Published - 2013
Externally published	Yes
Event	22nd International Conference on the Application of Accelerators in Research and Industry, CAARI 2012 - Fort Worth, TX, United States Duration: Aug 5 2012 → Aug 10 2012

Publication series

Name	AIP Conference Proceedings
Volume	1525
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Other

Other	22nd International Conference on the Application of Accelerators in Research and Industry, CAARI 2012
Country/Territory	United States
City	Fort Worth, TX
Period	8/5/12 → 8/10/12

Keywords

Dye-Sensitized Nanostructures
Free Electron Lasers
Ultrafast Spectroscopy
X-ray Photoelectron Spectroscopy

ASJC Scopus subject areas

General Physics and Astronomy

Online availability

10.1063/1.4802374

Library availability

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Shavorskiy, A., Cordones, A., Vura-Weis, J., Siefermann, K., Slaughter, D., Sturm, F., Weise, F., Bluhm, H., Strader, M., Cho, H., Lin, M. F., Bacellar, C., Khurmi, C., Hertlein, M., Guo, J., Tyliszczak, T., Prendergast, D., Coslovich, G., Robinson, J., ... Gessner, O. (2013). Time-resolved x-ray photoelectron spectroscopy techniques for real-time studies of interfacial charge transfer dynamics. In Application of Accelerators in Research and Industry - Twenty-Second International Conference (pp. 475-479). (AIP Conference Proceedings; Vol. 1525). https://doi.org/10.1063/1.4802374

Time-resolved x-ray photoelectron spectroscopy techniques for real-time studies of interfacial charge transfer dynamics. / Shavorskiy, Andrey; Cordones, Amy; Vura-Weis, Josh et al.
Application of Accelerators in Research and Industry - Twenty-Second International Conference. 2013. p. 475-479 (AIP Conference Proceedings; Vol. 1525).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Shavorskiy, A, Cordones, A, Vura-Weis, J, Siefermann, K, Slaughter, D, Sturm, F, Weise, F, Bluhm, H, Strader, M, Cho, H, Lin, MF, Bacellar, C, Khurmi, C, Hertlein, M, Guo, J, Tyliszczak, T, Prendergast, D, Coslovich, G, Robinson, J, Kaindl, RA, Schoenlein, RW, Belkacem, A, Weber, T, Neumark, DM, Leone, SR, Nordlund, D, Ogasawara, H, Nilsson, AR, Krupin, O, Turner, JJ, Schlotter, WF, Holmes, MR, Heimann, PA, Messerschmidt, M, Minitti, MP, Beye, M, Gul, S, Zhang, JZ, Huse, N & Gessner, O 2013, Time-resolved x-ray photoelectron spectroscopy techniques for real-time studies of interfacial charge transfer dynamics. in Application of Accelerators in Research and Industry - Twenty-Second International Conference. AIP Conference Proceedings, vol. 1525, pp. 475-479, 22nd International Conference on the Application of Accelerators in Research and Industry, CAARI 2012, Fort Worth, TX, United States, 8/5/12. https://doi.org/10.1063/1.4802374

Shavorskiy A, Cordones A, Vura-Weis J, Siefermann K, Slaughter D, Sturm F et al. Time-resolved x-ray photoelectron spectroscopy techniques for real-time studies of interfacial charge transfer dynamics. In Application of Accelerators in Research and Industry - Twenty-Second International Conference. 2013. p. 475-479. (AIP Conference Proceedings). doi: 10.1063/1.4802374

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title = "Time-resolved x-ray photoelectron spectroscopy techniques for real-time studies of interfacial charge transfer dynamics",

abstract = "X-ray based spectroscopy techniques are particularly well suited to gain access to local oxidation states and electronic dynamics in complex systems with atomic pinpoint accuracy. Traditionally, these techniques are applied in a quasi-static fashion that usually highlights the steady-state properties of a system rather than the fast dynamics that often define the system function on a molecular level. Novel x-ray spectroscopy techniques enabled by free electron lasers (FELs) and synchrotron based pump-probe schemes provide the opportunity to monitor intramolecular and interfacial charge transfer processes in real-time and with element and chemical specificity. Two complementary time-domain xray photoelectron spectroscopy techniques are presented that are applied at the Linac Coherent Light Source (LCLS) and the Advanced Light Source (ALS) to study charge transfer processes in N3 dye-sensitized ZnO semiconductor nanocrystals, which are at the heart of emerging light-harvesting technologies.",

keywords = "Dye-Sensitized Nanostructures, Free Electron Lasers, Ultrafast Spectroscopy, X-ray Photoelectron Spectroscopy",

author = "Andrey Shavorskiy and Amy Cordones and Josh Vura-Weis and Katrin Siefermann and Daniel Slaughter and Felix Sturm and Fabian Weise and Hendrik Bluhm and Matthew Strader and Hana Cho and Lin, {Ming Fu} and Camila Bacellar and Champak Khurmi and Marcus Hertlein and Jinghua Guo and Tolek Tyliszczak and David Prendergast and Giacomo Coslovich and Joseph Robinson and Kaindl, {Robert A.} and Schoenlein, {Robert W.} and Ali Belkacem and Thorsten Weber and Neumark, {Daniel M.} and Leone, {Stephen R.} and Dennis Nordlund and Hirohito Ogasawara and Nilsson, {Anders R.} and Oleg Krupin and Turner, {Joshua J.} and Schlotter, {William F.} and Holmes, {Michael R.} and Heimann, {Philip A.} and Marc Messerschmidt and Minitti, {Michael P.} and Martin Beye and Sheraz Gul and Zhang, {Jin Z.} and Nils Huse and Oliver Gessner",

year = "2013",

doi = "10.1063/1.4802374",

language = "English (US)",

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series = "AIP Conference Proceedings",

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T1 - Time-resolved x-ray photoelectron spectroscopy techniques for real-time studies of interfacial charge transfer dynamics

AU - Shavorskiy, Andrey

AU - Cordones, Amy

AU - Vura-Weis, Josh

AU - Siefermann, Katrin

AU - Slaughter, Daniel

AU - Sturm, Felix

AU - Weise, Fabian

AU - Bluhm, Hendrik

AU - Strader, Matthew

AU - Cho, Hana

AU - Lin, Ming Fu

AU - Bacellar, Camila

AU - Khurmi, Champak

AU - Hertlein, Marcus

AU - Guo, Jinghua

AU - Tyliszczak, Tolek

AU - Prendergast, David

AU - Coslovich, Giacomo

AU - Robinson, Joseph

AU - Kaindl, Robert A.

AU - Schoenlein, Robert W.

AU - Belkacem, Ali

AU - Weber, Thorsten

AU - Neumark, Daniel M.

AU - Leone, Stephen R.

AU - Nordlund, Dennis

AU - Ogasawara, Hirohito

AU - Nilsson, Anders R.

AU - Krupin, Oleg

AU - Turner, Joshua J.

AU - Schlotter, William F.

AU - Holmes, Michael R.

AU - Heimann, Philip A.

AU - Messerschmidt, Marc

AU - Minitti, Michael P.

AU - Beye, Martin

AU - Gul, Sheraz

AU - Zhang, Jin Z.

AU - Huse, Nils

AU - Gessner, Oliver

PY - 2013

Y1 - 2013

N2 - X-ray based spectroscopy techniques are particularly well suited to gain access to local oxidation states and electronic dynamics in complex systems with atomic pinpoint accuracy. Traditionally, these techniques are applied in a quasi-static fashion that usually highlights the steady-state properties of a system rather than the fast dynamics that often define the system function on a molecular level. Novel x-ray spectroscopy techniques enabled by free electron lasers (FELs) and synchrotron based pump-probe schemes provide the opportunity to monitor intramolecular and interfacial charge transfer processes in real-time and with element and chemical specificity. Two complementary time-domain xray photoelectron spectroscopy techniques are presented that are applied at the Linac Coherent Light Source (LCLS) and the Advanced Light Source (ALS) to study charge transfer processes in N3 dye-sensitized ZnO semiconductor nanocrystals, which are at the heart of emerging light-harvesting technologies.

AB - X-ray based spectroscopy techniques are particularly well suited to gain access to local oxidation states and electronic dynamics in complex systems with atomic pinpoint accuracy. Traditionally, these techniques are applied in a quasi-static fashion that usually highlights the steady-state properties of a system rather than the fast dynamics that often define the system function on a molecular level. Novel x-ray spectroscopy techniques enabled by free electron lasers (FELs) and synchrotron based pump-probe schemes provide the opportunity to monitor intramolecular and interfacial charge transfer processes in real-time and with element and chemical specificity. Two complementary time-domain xray photoelectron spectroscopy techniques are presented that are applied at the Linac Coherent Light Source (LCLS) and the Advanced Light Source (ALS) to study charge transfer processes in N3 dye-sensitized ZnO semiconductor nanocrystals, which are at the heart of emerging light-harvesting technologies.

KW - Dye-Sensitized Nanostructures

KW - Free Electron Lasers

KW - Ultrafast Spectroscopy

KW - X-ray Photoelectron Spectroscopy

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UR - http://www.scopus.com/inward/citedby.url?scp=84877729812&partnerID=8YFLogxK

U2 - 10.1063/1.4802374

DO - 10.1063/1.4802374

M3 - Conference contribution

AN - SCOPUS:84877729812

SN - 9780735411487

T3 - AIP Conference Proceedings

SP - 475

EP - 479

BT - Application of Accelerators in Research and Industry - Twenty-Second International Conference

T2 - 22nd International Conference on the Application of Accelerators in Research and Industry, CAARI 2012

Y2 - 5 August 2012 through 10 August 2012

ER -

Time-resolved x-ray photoelectron spectroscopy techniques for real-time studies of interfacial charge transfer dynamics

Abstract

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Other

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Online availability

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