Thiophene-metal-OXO compounds, one step closer to HDS active site models

Phillip R. Stafford; Thomas B. Rauchfuss

Thiophene-metal-OXO compounds, one step closer to HDS active site models

Phillip R. Stafford, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Conference article › peer-review

Abstract

Recent progress has been made in the preparation of metal thiophene compounds as mechanistic models for HDS catalysts. Since HDS catalysts are prepared from metal oxides it is of interest to examine the reactivity of the ternary system M-O-thiophene. This report will summarize the synthesis, structures, and reactivity of species of the type ReOR₄-where R = C₄H₃S, 2-MeC₄H₂S, benzothienyl, and dibenzothienyl. The behavior of these species will be contrasted with low valent Re compounds and oxo derivatives of other metals.

Original language	English (US)
Pages (from-to)	531
Number of pages	1
Journal	American Chemical Society, Division of Petroleum Chemistry, Preprints
Volume	39
Issue number	4
State	Published - Aug 1994
Event	Proceedings of the 208th National Meeting, American Chemical Society - Washington, DC, USA Duration: Aug 21 1994 → Aug 26 1994

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title = "Thiophene-metal-OXO compounds, one step closer to HDS active site models",

abstract = "Recent progress has been made in the preparation of metal thiophene compounds as mechanistic models for HDS catalysts. Since HDS catalysts are prepared from metal oxides it is of interest to examine the reactivity of the ternary system M-O-thiophene. This report will summarize the synthesis, structures, and reactivity of species of the type ReOR4-where R = C4H3S, 2-MeC4H2S, benzothienyl, and dibenzothienyl. The behavior of these species will be contrasted with low valent Re compounds and oxo derivatives of other metals.",

author = "Stafford, {Phillip R.} and Rauchfuss, {Thomas B.}",

year = "1994",

month = aug,

language = "English (US)",

volume = "39",

pages = "531",

journal = "American Chemical Society, Division of Petroleum Chemistry, Preprints",

issn = "0569-3799",

publisher = "American Chemical Society",

number = "4",

note = "Proceedings of the 208th National Meeting, American Chemical Society ; Conference date: 21-08-1994 Through 26-08-1994",

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T1 - Thiophene-metal-OXO compounds, one step closer to HDS active site models

AU - Stafford, Phillip R.

AU - Rauchfuss, Thomas B.

PY - 1994/8

Y1 - 1994/8

N2 - Recent progress has been made in the preparation of metal thiophene compounds as mechanistic models for HDS catalysts. Since HDS catalysts are prepared from metal oxides it is of interest to examine the reactivity of the ternary system M-O-thiophene. This report will summarize the synthesis, structures, and reactivity of species of the type ReOR4-where R = C4H3S, 2-MeC4H2S, benzothienyl, and dibenzothienyl. The behavior of these species will be contrasted with low valent Re compounds and oxo derivatives of other metals.

AB - Recent progress has been made in the preparation of metal thiophene compounds as mechanistic models for HDS catalysts. Since HDS catalysts are prepared from metal oxides it is of interest to examine the reactivity of the ternary system M-O-thiophene. This report will summarize the synthesis, structures, and reactivity of species of the type ReOR4-where R = C4H3S, 2-MeC4H2S, benzothienyl, and dibenzothienyl. The behavior of these species will be contrasted with low valent Re compounds and oxo derivatives of other metals.

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M3 - Conference article

AN - SCOPUS:0028480875

SN - 0569-3799

VL - 39

SP - 531

JO - American Chemical Society, Division of Petroleum Chemistry, Preprints

JF - American Chemical Society, Division of Petroleum Chemistry, Preprints

IS - 4

T2 - Proceedings of the 208th National Meeting, American Chemical Society

Y2 - 21 August 1994 through 26 August 1994

ER -

Thiophene-metal-OXO compounds, one step closer to HDS active site models

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