Thermochemical conversion of raw and defatted algal biomass via hydrothermal liquefaction and slow pyrolysis

Derek R. Vardon, Brajendra K. Sharma, Grant V. Blazina, Kishore Rajagopalan, Timothy J. Strathmann

Research output: Contribution to journalArticle

Abstract

Thermochemical conversion is a promising route for recovering energy from algal biomass. Two thermochemical processes, hydrothermal liquefaction (HTL: 300 °C and 10-12. MPa) and slow pyrolysis (heated to 450 °C at a rate of 50 °C/min), were used to produce bio-oils from Scenedesmus (raw and defatted) and Spirulina biomass that were compared against Illinois shale oil. Although both thermochemical conversion routes produced energy dense bio-oil (35-37. MJ/kg) that approached shale oil (41. MJ/kg), bio-oil yields (24-45%) and physico-chemical characteristics were highly influenced by conversion route and feedstock selection. Sharp differences were observed in the mean bio-oil molecular weight (pyrolysis 280-360. Da; HTL 700-1330. Da) and the percentage of low boiling compounds (bp < 400 °C) (pyrolysis 62-66%; HTL 45-54%). Analysis of the energy consumption ratio (ECR) also revealed that for wet algal biomass (80% moisture content), HTL is more favorable (ECR 0.44-0.63) than pyrolysis (ECR 0.92-1.24) due to required water volatilization in the latter technique.

LanguageEnglish (US)
Pages178-187
Number of pages10
JournalBioresource Technology
Volume109
DOIs
StatePublished - Apr 1 2012

Fingerprint

Liquefaction
liquefaction
pyrolysis
Oils
Biomass
Pyrolysis
Shale oil
Energy utilization
oil
oil shale
biomass
Spirulina
volatilization
Vaporization
Boiling liquids
Feedstocks
energy
moisture content
Moisture
Molecular weight

Keywords

  • Algae
  • Hydrothermal liquefaction
  • Pyrolysis
  • Scenedesmus
  • Spirulina

ASJC Scopus subject areas

  • Bioengineering
  • Environmental Engineering
  • Renewable Energy, Sustainability and the Environment
  • Waste Management and Disposal

Cite this

Thermochemical conversion of raw and defatted algal biomass via hydrothermal liquefaction and slow pyrolysis. / Vardon, Derek R.; Sharma, Brajendra K.; Blazina, Grant V.; Rajagopalan, Kishore; Strathmann, Timothy J.

In: Bioresource Technology, Vol. 109, 01.04.2012, p. 178-187.

Research output: Contribution to journalArticle

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