Theory of the radiative lifetime of the 3B1 state of SO2

Philip Phillips; Ernest R. Davidson

doi:10.1002/jcc.540040308

Theory of the radiative lifetime of the ³B₁ state of SO₂

Research output: Contribution to journal › Article › peer-review

Abstract

Interchange and many‐body perturbation theory are applied to the calculation of the radiative lifetime of the ³B₁ state of SO₂. The radiative lifetime of ³B₁ SO₂ is predicted to be 7.6 msec, in excellent agreement with the experimental collision‐free phosphorescence lifetime. As a separate calculation, interchange perturbation theory is used to determine the radiative lifetime of the ¹A₁ state of CH₂.

Original language	English (US)
Pages (from-to)	337-344
Number of pages	8
Journal	Journal of Computational Chemistry
Volume	4
Issue number	3
DOIs	https://doi.org/10.1002/jcc.540040308
State	Published - 1983
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Computational Mathematics

Online availability

10.1002/jcc.540040308

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Cite this

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title = "Theory of the radiative lifetime of the 3B1 state of SO2",

abstract = "Interchange and many‐body perturbation theory are applied to the calculation of the radiative lifetime of the 3B1 state of SO2. The radiative lifetime of 3B1 SO2 is predicted to be 7.6 msec, in excellent agreement with the experimental collision‐free phosphorescence lifetime. As a separate calculation, interchange perturbation theory is used to determine the radiative lifetime of the 1A1 state of CH2.",

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AB - Interchange and many‐body perturbation theory are applied to the calculation of the radiative lifetime of the 3B1 state of SO2. The radiative lifetime of 3B1 SO2 is predicted to be 7.6 msec, in excellent agreement with the experimental collision‐free phosphorescence lifetime. As a separate calculation, interchange perturbation theory is used to determine the radiative lifetime of the 1A1 state of CH2.

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