The unexpectedly slow approach to thermodynamic equilibrium of the silicate anions in aqueous tetramethylammonium silicate solutions

C. T.G. Knight, R. James Kirkpatrick, Eric Oldfield

Research output: Contribution to journalArticlepeer-review

Abstract

Contrary to the widely accepted picture of the dynamics of alkaline silicate solutions, tetramethylammonium silicate solutions require many days to re-establish thermodynamic equilibrium following a perturbation, as monitored by 29Si n.m.r. spectroscopy.

Original languageEnglish (US)
Pages (from-to)66-67
Number of pages2
JournalJournal of the Chemical Society Chemical Communications
Volume1
DOIs
StatePublished - 1986

ASJC Scopus subject areas

  • Molecular Medicine

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