@article{738fb457def44cdcb0b422424f95bb23,
title = "The first transition metal thiosulphinate and sulphenate esters: [Ir(η2-S2OMe)(dppe)2]2+ and [Ir(η1-SOMe)(MeNC)(dppe)2]2+ [dppe = 1,2-bis(diphenylphosphino)ethane]",
abstract = "[Ir(S2O)(dppe)2]+ reacts with MeOSO 2F giving [Ir(η2-S2OMe)(dppe) 2]2+ which was characterised by X-ray crystallography and can be converted into [Ir(η1-SOMe)(MeNC)(dppe)2] 2+ [dppe = 1,2-bis(diphenylphosphino)ethane].",
author = "Hoots, \{John E.\} and Rauchfuss, \{Thomas B.\} and Wilson, \{Scott R.\}",
note = "SOC., CHEM. COMMUN., 1983 2). A decoupling experiment showed that the rnetu protons were definitely on a phenyl ring unique from that which bears the high-field ortho-phenyl protons. This behaviour indicates unusual shielding interactions in (3) which, we suggest, reflect considerable steric crowding. In summary, we have shown how the reactions of the co- ordinated S20 moiety, and in principle related hetero-cumulenes, can be used to prepare stable derivatives of highly reactive organosulphur compounds. Acknowledgment is made to the Petroleum Research Fund and the National Science Foundation. T. B. R. also acknowl- edges fellowships from the A. P. Sloan and the Camille and Henry Dreyfus Foundations. Received, 14th July 1983; Corn. 945 References E. Kuhle, 'The Chemistry of the Sulphenic Acids,' Georg Thieme Publishers, Stuttgart, 1973. L. Marko, B. Mark6-Monostory, T. Madach, and H. Vahren-kamp, Angew. Chem., Int. Ed. Engl., 1980, 19, 226. A. P. Ginsberg and W. E. Lindsell, Chem. Commun., 1971,232. C. M. Bolinger, T. B. Rauchfuss, and S. R. Wilson, J. Am. Chem. Sac., 1981, 103, 5620. G. Schrnid and G. Ritter, Angew. Chem., Int. Ed. Engl., 1975, 14, 645. J. E. Hoots and T. B. Rauchfuss, Inorg. Chem., in the press. A. P. Ginsberg and W. E. Lindsell, Inorg. Chem., 1973, 12, 1983. G. Schmid and G. Ritter, Chem. Ber., 1975, 108, 3008. W. D. Bonds, Jr., and J. A. Ibers, J. Am. Chem. SOC.,1972,94, 3413.",
year = "1983",
doi = "10.1039/C39830001226",
language = "English (US)",
pages = "1226--1228",
journal = "Journal of the Chemical Society D: Chemical Communications",
issn = "0022-4936",
publisher = "Chemical Society",
number = "21",
}