Abstract
O-(Silacyclobutyl) ketene acetals derived from esters, thiol esters, and amides reacted with a variety of aldehydes at room temperature without the need for catalysts. The O,O-ketene acetal of E-configuration reacted rapidly to afford the syn aldol products with high diastereoselectivity (93/7∼99/1).
| Original language | English (US) |
|---|---|
| Pages (from-to) | 988-990 |
| Number of pages | 3 |
| Journal | Journal of Organic Chemistry |
| Volume | 58 |
| Issue number | 5 |
| DOIs | |
| State | Published - 1993 |
ASJC Scopus subject areas
- Organic Chemistry
Fingerprint
Dive into the research topics of 'The Chemistry of Enoxysilacyclobutanes: Highly Selective, Uncatalyzed Aldol Additions'. Together they form a unique fingerprint.Cite this
- APA
- Standard
- Harvard
- Vancouver
- Author
- BIBTEX
- RIS