The chemistry of C6S10: A channel structure for C6S10(CS2)0.5 and access to the versatile DMAD·C3S4O (DMAD = dimethylacetylenedicarboxylate)

Xiaoguang Yang; Thomas B. Rauchfuss; Scott Wilson

doi:10.1039/C39900000034

The chemistry of C₆S₁₀: A channel structure for C₆S₁₀(CS₂)_0.5 and access to the versatile DMAD·C₃S₄O (DMAD = dimethylacetylenedicarboxylate)

Xiaoguang Yang, Thomas B. Rauchfuss, Scott Wilson

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Treatment of (Et₄N)₂[Zn(C₃S ₅)₂] with SO₂Cl₂ gives molecular C₆S₁₀ (1), structurally characterized as (1)·(CS₂)_0.5, which has a channel structure; a two step conversion affords bicyclic tetrathiaindenone OC₃S ₄·C₂(CO₂Me)₂ which is used to make new alkenedithiolate derivatives.

Original language	English (US)
Pages (from-to)	34-36
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/C39900000034
State	Published - 1990

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39900000034

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abstract = "Treatment of (Et4N)2[Zn(C3S 5)2] with SO2Cl2 gives molecular C6S10 (1), structurally characterized as (1)·(CS2)0.5, which has a channel structure; a two step conversion affords bicyclic tetrathiaindenone OC3S 4·C2(CO2Me)2 which is used to make new alkenedithiolate derivatives.",

author = "Xiaoguang Yang and Rauchfuss, {Thomas B.} and Scott Wilson",

year = "1990",

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