The aerobic oxidation of a Pd(II) dimethyl complex leads to selective ethane elimination from a Pd(III) intermediate

Keyphrases

• Ethane 100%
• Dimethyl 100%
• Pd(II) 100%
• Aerobic Oxidation 100%
• Pd(III) 100%
• Tert-butyl 50%
• C-H Bond 50%
• C-C Bond Formation 50%
• Cyclic Voltammetry Studies 25%
• Pd Catalyst 25%
• Mechanistic Studies 25%
• Bond Cleavage 25%
• Acetone 25%
• Superoxide 25%
• Heterotic 25%
• Selective Formation 25%
• Inner-sphere Mechanism 25%
• Terminal Alkynes 25%
• Two-electron Oxidation 25%
• Methyl Transfer 25%
• Spin Trapping 25%
• Addition Reaction 25%
• Crossing Experiment 25%
• Cumene Hydroperoxide 25%
• Pd(II) Complexes 25%
• Pyridinophane 25%
• 5,5-dimethyl-1-pyrroline N-oxide 25%
• Non-radical Mechanism 25%
• Aerobic Oxidative Coupling 25%

Chemistry

• C-C Bond Formation 100%
• Cyclic Voltammetry 50%
• Alkyne 50%
• Mechanistic Study 50%
• Methyl Group 50%
• Superoxide 50%
• N-Oxide 50%
• Addition Reaction 50%
• 1-Pyrroline 50%
• Cumene Hydroperoxide 50%
• ROOH 50%