The addition of isocyanides to ReS4-: [3 + 1] cycloaddition to S=M=S

Daniel E. Schwarz; Thomas B. Rauchfuss

doi:10.1039/b000932f

The addition of isocyanides to ReS₄-: [3 + 1] cycloaddition to S=M=S

Daniel E. Schwarz
, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Isocyanides undergo [3 + 1] cycloadditions to ReS₄- to give dithiocarboimidate derivatives, Re(S)(S₄)(S₂CNR)- and Re₂S₅(S₂CNR)₂^2- , which undergo S-atom transfer and, in the case of the monometallic species, N-alkylation.

Original language	English (US)
Pages (from-to)	1123-1124
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/b000932f
State	Published - Jul 7 2000

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Online availability

10.1039/b000932f

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Cite this

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title = "The addition of isocyanides to ReS4-: [3 + 1] cycloaddition to S=M=S",

abstract = "Isocyanides undergo [3 + 1] cycloadditions to ReS4- to give dithiocarboimidate derivatives, Re(S)(S4)(S2CNR)- and Re2S5(S2CNR)22- , which undergo S-atom transfer and, in the case of the monometallic species, N-alkylation.",

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AU - Rauchfuss, Thomas B.

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N2 - Isocyanides undergo [3 + 1] cycloadditions to ReS4- to give dithiocarboimidate derivatives, Re(S)(S4)(S2CNR)- and Re2S5(S2CNR)22- , which undergo S-atom transfer and, in the case of the monometallic species, N-alkylation.

AB - Isocyanides undergo [3 + 1] cycloadditions to ReS4- to give dithiocarboimidate derivatives, Re(S)(S4)(S2CNR)- and Re2S5(S2CNR)22- , which undergo S-atom transfer and, in the case of the monometallic species, N-alkylation.

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