TY - JOUR
T1 - Tertiary Phosphine Adducts of Manganese(II) Dicyclopentadienide. Magnetic Studies and Structural Characterization of “Tilted” Cyclopentadienyl Rings
AU - Howard, Christopher G.
AU - Girolami, Gregory S.
AU - Wilkinson, Geoffrey
AU - Thornton-Pett, Mark
AU - Hursthouse, Michael B.
PY - 1984
Y1 - 1984
N2 - Adducts of manganese(II) dicyclopentadienide, Mn(C5H5)2, and of Mn(C5H4CH3)2 with the unidentate tertiary phosphines PMe3, PMe2Ph, PMePh2, and PEt3 and with the chelating phosphine Me2PCH2CH2PMe2 (dmpe) have been synthesized. The structures of (C5H5)2Mn(PMe3), (C5H5)2Mn(PMePh2), and (C5H5)2Mn(dmpe) have been determined by X-ray crystallographic studies, and “tilted” planar cyclopentadienyl rings have been observed. Electron paramagnetic resonance spectra as well as magnetic susceptibilities have been determined.
AB - Adducts of manganese(II) dicyclopentadienide, Mn(C5H5)2, and of Mn(C5H4CH3)2 with the unidentate tertiary phosphines PMe3, PMe2Ph, PMePh2, and PEt3 and with the chelating phosphine Me2PCH2CH2PMe2 (dmpe) have been synthesized. The structures of (C5H5)2Mn(PMe3), (C5H5)2Mn(PMePh2), and (C5H5)2Mn(dmpe) have been determined by X-ray crystallographic studies, and “tilted” planar cyclopentadienyl rings have been observed. Electron paramagnetic resonance spectra as well as magnetic susceptibilities have been determined.
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U2 - 10.1021/ja00319a022
DO - 10.1021/ja00319a022
M3 - Article
AN - SCOPUS:0021754859
SN - 0002-7863
VL - 106
SP - 2033
EP - 2040
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 7
ER -