Temporal and spatial characteristics of ozone depletion events from measurements in the Arctic

J. W. Halfacre, T. N. Knepp, P. B. Shepson, C. R. Thompson, K. A. Pratt, Bo Li, P. K. Peterson, S. J. Walsh, W. R. Simpson, P. A. Matrai, J. W. Bottenheim, S. Netcheva, D. K. Perovich, A. Richter

Research output: Contribution to journalArticle

Abstract

Following polar sunrise in the Arctic springtime, tropospheric ozone episodically decreases rapidly to near-zero levels during ozone depletion events (ODEs). Many uncertainties remain in our understanding of ODE characteristics, including the temporal and spatial scales, as well as environmental drivers. Measurements of ozone, bromine monoxide (BrO), and meteorology were obtained during several deployments of autonomous, ice-tethered buoys (O-Buoys) from both coastal sites and over the Arctic Ocean; these data were used to characterize observed ODEs. Detected decreases in surface ozone levels during the onset of ODEs corresponded to a median estimated apparent ozone depletion timescale (based on both chemistry and the advection of O3-depleted air) of 11 h. If assumed to be dominated by chemical mechanisms, these timescales would correspond to larger-than-observed BrO mole fractions based on known chemistry and assumed other radical levels. Using backward air mass trajectories and an assumption that transport mechanisms dominate observations, the spatial scales for ODEs (defined by time periods in which ozone levels ≤ 15 nmol mol -1) were estimated to be 877 km (median), while areas estimated to represent major ozone depletions (<10 nmol mol-1) had dimensions of 282 km (median). These observations point to a heterogeneous boundary layer with localized regions of active, ozone-destroying halogen chemistry, interspersed among larger regions of previously depleted air that retain reduced ozone levels through hindered atmospheric mixing. Based on the estimated size distribution, Monte Carlo simulations showed it was statistically possible that all ODEs observed could have originated upwind, followed by transport to the measurement site. Local wind speed averages were low during most ODEs (median of ∼3.6 m s-1), and there was no apparent dependence on local temperature.

Original languageEnglish (US)
Pages (from-to)4875-4894
Number of pages20
JournalAtmospheric Chemistry and Physics
Volume14
Issue number10
DOIs
StatePublished - May 20 2014

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ozone depletion
ozone
bromine
timescale
air
halogen
meteorology
air mass
advection
boundary layer
wind velocity
trajectory
ice

ASJC Scopus subject areas

  • Atmospheric Science

Cite this

Halfacre, J. W., Knepp, T. N., Shepson, P. B., Thompson, C. R., Pratt, K. A., Li, B., ... Richter, A. (2014). Temporal and spatial characteristics of ozone depletion events from measurements in the Arctic. Atmospheric Chemistry and Physics, 14(10), 4875-4894. https://doi.org/10.5194/acp-14-4875-2014

Temporal and spatial characteristics of ozone depletion events from measurements in the Arctic. / Halfacre, J. W.; Knepp, T. N.; Shepson, P. B.; Thompson, C. R.; Pratt, K. A.; Li, Bo; Peterson, P. K.; Walsh, S. J.; Simpson, W. R.; Matrai, P. A.; Bottenheim, J. W.; Netcheva, S.; Perovich, D. K.; Richter, A.

In: Atmospheric Chemistry and Physics, Vol. 14, No. 10, 20.05.2014, p. 4875-4894.

Research output: Contribution to journalArticle

Halfacre, JW, Knepp, TN, Shepson, PB, Thompson, CR, Pratt, KA, Li, B, Peterson, PK, Walsh, SJ, Simpson, WR, Matrai, PA, Bottenheim, JW, Netcheva, S, Perovich, DK & Richter, A 2014, 'Temporal and spatial characteristics of ozone depletion events from measurements in the Arctic', Atmospheric Chemistry and Physics, vol. 14, no. 10, pp. 4875-4894. https://doi.org/10.5194/acp-14-4875-2014
Halfacre, J. W. ; Knepp, T. N. ; Shepson, P. B. ; Thompson, C. R. ; Pratt, K. A. ; Li, Bo ; Peterson, P. K. ; Walsh, S. J. ; Simpson, W. R. ; Matrai, P. A. ; Bottenheim, J. W. ; Netcheva, S. ; Perovich, D. K. ; Richter, A. / Temporal and spatial characteristics of ozone depletion events from measurements in the Arctic. In: Atmospheric Chemistry and Physics. 2014 ; Vol. 14, No. 10. pp. 4875-4894.
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