TY - JOUR
T1 - Temperature-dependent optical properties of titanium nitride
AU - Briggs, Justin A.
AU - Naik, Gururaj V.
AU - Zhao, Yang
AU - Petach, Trevor A.
AU - Sahasrabuddhe, Kunal
AU - Goldhaber-Gordon, David
AU - Melosh, Nicholas A.
AU - Dionne, Jennifer A.
N1 - Funding Information:
J.A.B. would like to thank everyone at HeatWave Labs. J.A.B. was supported by NSF GRF (2012122469). This work is part of the “Light-Material Interactions in Energy Conversion” Energy Frontier Research Center under U.S. DOE, Office of Science, Office of Basic Energy Sciences award DE-SC0001293. X-ray studies were supported under DOE LDRD award DE-AC02-76F00515. Part of this work was performed at Stanford's SNSF and SNF.
Publisher Copyright:
© 2017 Author(s).
PY - 2017/3/6
Y1 - 2017/3/6
N2 - The refractory metal titanium nitride is promising for high-temperature nanophotonic and plasmonic applications, but its optical properties have not been studied at temperatures exceeding 400 °C. Here, we perform in-situ high-temperature ellipsometry to quantify the permittivity of TiN films from room temperature to 1258 °C. We find that the material becomes more absorptive at higher temperatures but maintains its metallic character throughout visible and near infrared frequencies. X-ray diffraction, atomic force microscopy, and mass spectrometry confirm that TiN retains its bulk crystal quality and that thermal cycling increases the surface roughness, reduces the lattice constant, and reduces the carbon and oxygen contaminant concentrations. The changes in the optical properties of the material are highly reproducible upon repeated heating and cooling, and the room-temperature properties are fully recoverable after cooling. Using the measured high-temperature permittivity, we compute the emissivity, surface plasmon polariton propagation length, and two localized surface plasmon resonance figures of merit as functions of temperature. Our results indicate that titanium nitride is a viable plasmonic material throughout the full temperature range explored.
AB - The refractory metal titanium nitride is promising for high-temperature nanophotonic and plasmonic applications, but its optical properties have not been studied at temperatures exceeding 400 °C. Here, we perform in-situ high-temperature ellipsometry to quantify the permittivity of TiN films from room temperature to 1258 °C. We find that the material becomes more absorptive at higher temperatures but maintains its metallic character throughout visible and near infrared frequencies. X-ray diffraction, atomic force microscopy, and mass spectrometry confirm that TiN retains its bulk crystal quality and that thermal cycling increases the surface roughness, reduces the lattice constant, and reduces the carbon and oxygen contaminant concentrations. The changes in the optical properties of the material are highly reproducible upon repeated heating and cooling, and the room-temperature properties are fully recoverable after cooling. Using the measured high-temperature permittivity, we compute the emissivity, surface plasmon polariton propagation length, and two localized surface plasmon resonance figures of merit as functions of temperature. Our results indicate that titanium nitride is a viable plasmonic material throughout the full temperature range explored.
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U2 - 10.1063/1.4977840
DO - 10.1063/1.4977840
M3 - Article
AN - SCOPUS:85014573581
VL - 110
JO - Applied Physics Letters
JF - Applied Physics Letters
SN - 0003-6951
IS - 10
M1 - 101901
ER -