Synthesis, Structure, and Electrical Properties of [(MeCp)5V5S6][(TCNQ)2]

C. Mark Bolinger, James Darkwa, Gordon Gammie, Thomas B. Rauchfuss, Scott R. Wilson, Steven D. Gammon, Joseph W. Lyding

Research output: Contribution to journalArticle

Abstract

Desulfurization of (MeCp)2V2S4 with PBu3 gives (MeCp)4V4S4 (1) and (MeCp)5V5S6 (2). Compounds 1 and 2 were characterized by 1H NMR spectroscopy and mass spectrometry. Compound 2 forms the charge-transfer salt [2] [(TCNQ)2] which was characterized by X-ray crystallography as its CH2Cl2 solvate. The cluster consists of a trigonal-bipyramidal V5 core inside of a trigonal prism of six sulfur atoms. Four-probe conductivity measurements show that [2] [(TCNQ)2] is a n-type semiconductor (Eg ≈ 0.25 eV).

Original languageEnglish (US)
Pages (from-to)2386-2388
Number of pages3
JournalOrganometallics
Volume5
Issue number11
DOIs
StatePublished - Jan 1 1986

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Bolinger, C. M., Darkwa, J., Gammie, G., Rauchfuss, T. B., Wilson, S. R., Gammon, S. D., & Lyding, J. W. (1986). Synthesis, Structure, and Electrical Properties of [(MeCp)5V5S6][(TCNQ)2]. Organometallics, 5(11), 2386-2388. https://doi.org/10.1021/om00142a039