Synthesis of tetradentate bisamino-bisthiol complexes of oxorhenium(V) as structural mimics of steroids

Yuichi Sugano; John A. Katzenellenbogen

doi:10.1016/0960-894X(96)00029-7

Synthesis of tetradentate bisamino-bisthiol complexes of oxorhenium(V) as structural mimics of steroids

Yuichi Sugano
, John A. Katzenellenbogen

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Two tetradentate chelate systems have been synthesized in order to prepare metal complexes with oxorhenium(V) whose structures will mimic that of steroids. The chelate system with amide/amine/thioether/thiol donor sites failed to give a stable complex, but the corresponding diamine chelate gave a stable complex.

Original language	English (US)
Pages (from-to)	361-366
Number of pages	6
Journal	Bioorganic and Medicinal Chemistry Letters
Volume	6
Issue number	4
DOIs	https://doi.org/10.1016/0960-894X(96)00029-7
State	Published - Feb 20 1996

ASJC Scopus subject areas

Biochemistry
Molecular Medicine
Molecular Biology
Pharmaceutical Science
Drug Discovery
Clinical Biochemistry
Organic Chemistry

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10.1016/0960-894X(96)00029-7

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title = "Synthesis of tetradentate bisamino-bisthiol complexes of oxorhenium(V) as structural mimics of steroids",

abstract = "Two tetradentate chelate systems have been synthesized in order to prepare metal complexes with oxorhenium(V) whose structures will mimic that of steroids. The chelate system with amide/amine/thioether/thiol donor sites failed to give a stable complex, but the corresponding diamine chelate gave a stable complex.",

author = "Yuichi Sugano and Katzenellenbogen, \{John A.\}",

note = "We are grateful for support of this research through grants from the National Institutes of Health (PHS 5R01 DK15556) and Sankyo Co. Ltd.",

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AU - Sugano, Yuichi

AU - Katzenellenbogen, John A.

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PY - 1996/2/20

Y1 - 1996/2/20

N2 - Two tetradentate chelate systems have been synthesized in order to prepare metal complexes with oxorhenium(V) whose structures will mimic that of steroids. The chelate system with amide/amine/thioether/thiol donor sites failed to give a stable complex, but the corresponding diamine chelate gave a stable complex.

AB - Two tetradentate chelate systems have been synthesized in order to prepare metal complexes with oxorhenium(V) whose structures will mimic that of steroids. The chelate system with amide/amine/thioether/thiol donor sites failed to give a stable complex, but the corresponding diamine chelate gave a stable complex.

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U2 - 10.1016/0960-894X(96)00029-7

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M3 - Article

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Synthesis of tetradentate bisamino-bisthiol complexes of oxorhenium(V) as structural mimics of steroids

Abstract

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