Synthesis of organometallic solids by protonation of Cp*M(CN)3n- (M = Rh, Ir, Ru)

Stephen M. Contakes; Michael Schmidt; Thomas B. Rauchfuss

doi:10.1039/a902115i

Synthesis of organometallic solids by protonation of Cp*M(CN)₃n- (M = Rh, Ir, Ru)

Stephen M. Contakes
, Michael Schmidt
, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Protonation of aqueous acetone solutions of [Cp*Ir(CN)₃]- produces the two-dimensional organometallic solid (H₃O-[Cp*Ir(CN)₃]·Me₂CO wherein 14 Å diameter channels (Ir₄C₈N₈O₄) contain exchangeable solvent molecules; the analogous Ru and Rh tricyanide complexes are also susceptible to proton-induced polymerization.

Original language	English (US)
Pages (from-to)	1183-1184
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/a902115i
State	Published - Jul 7 1999

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Online availability

10.1039/a902115i

Library availability

Discover UIUC Full Text

Cite this

@article{b7da1aefd5a34b24ae74a67e255d084e,

title = "Synthesis of organometallic solids by protonation of Cp*M(CN)3n- (M = Rh, Ir, Ru)",

abstract = "Protonation of aqueous acetone solutions of [Cp*Ir(CN)3]- produces the two-dimensional organometallic solid (H3O-[Cp*Ir(CN)3]·Me2CO wherein 14 {\AA} diameter channels (Ir4C8N8O4) contain exchangeable solvent molecules; the analogous Ru and Rh tricyanide complexes are also susceptible to proton-induced polymerization.",

author = "Contakes, \{Stephen M.\} and Michael Schmidt and Rauchfuss, \{Thomas B.\}",

year = "1999",

month = jul,

day = "7",

doi = "10.1039/a902115i",

language = "English (US)",

pages = "1183--1184",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "13",

}

TY - JOUR

T1 - Synthesis of organometallic solids by protonation of Cp*M(CN)3n- (M = Rh, Ir, Ru)

AU - Contakes, Stephen M.

AU - Schmidt, Michael

AU - Rauchfuss, Thomas B.

PY - 1999/7/7

Y1 - 1999/7/7

N2 - Protonation of aqueous acetone solutions of [Cp*Ir(CN)3]- produces the two-dimensional organometallic solid (H3O-[Cp*Ir(CN)3]·Me2CO wherein 14 Å diameter channels (Ir4C8N8O4) contain exchangeable solvent molecules; the analogous Ru and Rh tricyanide complexes are also susceptible to proton-induced polymerization.

AB - Protonation of aqueous acetone solutions of [Cp*Ir(CN)3]- produces the two-dimensional organometallic solid (H3O-[Cp*Ir(CN)3]·Me2CO wherein 14 Å diameter channels (Ir4C8N8O4) contain exchangeable solvent molecules; the analogous Ru and Rh tricyanide complexes are also susceptible to proton-induced polymerization.

UR - https://www.scopus.com/pages/publications/0033532850

UR - https://www.scopus.com/pages/publications/0033532850#tab=citedBy

U2 - 10.1039/a902115i

DO - 10.1039/a902115i

M3 - Article

AN - SCOPUS:0033532850

SN - 1359-7345

SP - 1183

EP - 1184

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -