Synthesis of organometallic solids by protonation of Cp*M(CN)3n- (M = Rh, Ir, Ru)

Stephen M. Contakes, Michael Schmidt, Thomas B. Rauchfuss

Research output: Contribution to journalArticlepeer-review

Abstract

Protonation of aqueous acetone solutions of [Cp*Ir(CN)3]- produces the two-dimensional organometallic solid (H3O-[Cp*Ir(CN)3]·Me2CO wherein 14 Å diameter channels (Ir4C8N8O4) contain exchangeable solvent molecules; the analogous Ru and Rh tricyanide complexes are also susceptible to proton-induced polymerization.

Original languageEnglish (US)
Pages (from-to)1183-1184
Number of pages2
JournalChemical Communications
Issue number13
DOIs
StatePublished - Jul 7 1999

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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