Synthesis of organometallic solids by protonation of Cp*M(CN)3n- (M = Rh, Ir, Ru)

Stephen M. Contakes; Michael Schmidt; Thomas B. Rauchfuss

doi:10.1039/a902115i

Synthesis of organometallic solids by protonation of Cp*M(CN)₃n- (M = Rh, Ir, Ru)

Stephen M. Contakes, Michael Schmidt, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Protonation of aqueous acetone solutions of [Cp*Ir(CN)₃]- produces the two-dimensional organometallic solid (H₃O-[Cp*Ir(CN)₃]·Me₂CO wherein 14 Å diameter channels (Ir₄C₈N₈O₄) contain exchangeable solvent molecules; the analogous Ru and Rh tricyanide complexes are also susceptible to proton-induced polymerization.

Original language	English (US)
Pages (from-to)	1183-1184
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/a902115i
State	Published - Jul 7 1999

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Online availability

10.1039/a902115i

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Cite this

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abstract = "Protonation of aqueous acetone solutions of [Cp*Ir(CN)3]- produces the two-dimensional organometallic solid (H3O-[Cp*Ir(CN)3]·Me2CO wherein 14 {\AA} diameter channels (Ir4C8N8O4) contain exchangeable solvent molecules; the analogous Ru and Rh tricyanide complexes are also susceptible to proton-induced polymerization.",

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