Synthesis of an amine-oleate derivative using an ionic liquid catalyst

Biswas Atanu; Brajendra Kumar Sharma; Kenneth M. Doll; Sevim Z. Erhan; Julious L. Wlllett And; H. N. Cheng

doi:10.1021/jf901401s

Synthesis of an amine-oleate derivative using an ionic liquid catalyst

Biswas Atanu, Brajendra Kumar Sharma, Kenneth M. Doll, Sevim Z. Erhan, Julious L. Wlllett And, H. N. Cheng

Research output: Contribution to journal › Article › peer-review

Abstract

A facile (and environmentally friendly) reaction between epoxidized methyl oleate and aniline to produce an oleate-aniline adduct, without the formation of fatty amide, was discovered. This reaction was carried out neat, with a catalytic amount of an ionic liquid. No solvent was used, no byproducts were produced, and the ionic liquid could be recovered and recycled. The reaction products were fully characterized by NMR and GC-MS.

Original language	English (US)
Pages (from-to)	8136-8141
Number of pages	6
Journal	Journal of Agricultural and Food Chemistry
Volume	57
Issue number	18
DOIs	https://doi.org/10.1021/jf901401s
State	Published - Sep 23 2009
Externally published	Yes

Keywords

Branched oleochemical
Epoxidized methyl oleate aniline
Lubrication fluid

ASJC Scopus subject areas

General Chemistry
General Agricultural and Biological Sciences

Online availability

10.1021/jf901401s

Library availability

Discover UIUC Full Text

Cite this

@article{c43366d19270484b85a97ee8b430b446,

title = "Synthesis of an amine-oleate derivative using an ionic liquid catalyst",

abstract = "A facile (and environmentally friendly) reaction between epoxidized methyl oleate and aniline to produce an oleate-aniline adduct, without the formation of fatty amide, was discovered. This reaction was carried out neat, with a catalytic amount of an ionic liquid. No solvent was used, no byproducts were produced, and the ionic liquid could be recovered and recycled. The reaction products were fully characterized by NMR and GC-MS.",

keywords = "Branched oleochemical, Epoxidized methyl oleate aniline, Lubrication fluid",

author = "Biswas Atanu and Sharma, {Brajendra Kumar} and Doll, {Kenneth M.} and Erhan, {Sevim Z.} and {Wlllett And}, {Julious L.} and Cheng, {H. N.}",

year = "2009",

month = sep,

day = "23",

doi = "10.1021/jf901401s",

language = "English (US)",

volume = "57",

pages = "8136--8141",

journal = "Journal of Agricultural and Food Chemistry",

issn = "0021-8561",

publisher = "American Chemical Society",

number = "18",

}

TY - JOUR

T1 - Synthesis of an amine-oleate derivative using an ionic liquid catalyst

AU - Atanu, Biswas

AU - Sharma, Brajendra Kumar

AU - Doll, Kenneth M.

AU - Erhan, Sevim Z.

AU - Wlllett And, Julious L.

AU - Cheng, H. N.

PY - 2009/9/23

Y1 - 2009/9/23

N2 - A facile (and environmentally friendly) reaction between epoxidized methyl oleate and aniline to produce an oleate-aniline adduct, without the formation of fatty amide, was discovered. This reaction was carried out neat, with a catalytic amount of an ionic liquid. No solvent was used, no byproducts were produced, and the ionic liquid could be recovered and recycled. The reaction products were fully characterized by NMR and GC-MS.

AB - A facile (and environmentally friendly) reaction between epoxidized methyl oleate and aniline to produce an oleate-aniline adduct, without the formation of fatty amide, was discovered. This reaction was carried out neat, with a catalytic amount of an ionic liquid. No solvent was used, no byproducts were produced, and the ionic liquid could be recovered and recycled. The reaction products were fully characterized by NMR and GC-MS.

KW - Branched oleochemical

KW - Epoxidized methyl oleate aniline

KW - Lubrication fluid

UR - http://www.scopus.com/inward/record.url?scp=70349335649&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=70349335649&partnerID=8YFLogxK

U2 - 10.1021/jf901401s

DO - 10.1021/jf901401s

M3 - Article

C2 - 19719124

AN - SCOPUS:70349335649

SN - 0021-8561

VL - 57

SP - 8136

EP - 8141

JO - Journal of Agricultural and Food Chemistry

JF - Journal of Agricultural and Food Chemistry

IS - 18

ER -

Synthesis of an amine-oleate derivative using an ionic liquid catalyst

Abstract

Keywords

ASJC Scopus subject areas

Online availability

Library availability

Related links

Fingerprint

Cite this