Synthesis of a New Type of Metal Dithiolene Complex via an Induced Reaction of Acetylenes with a Ruthenium Sulfide

Thomas Rauchfuss, Damian P.S. Rodgers, Scott R. Wilson

Research output: Contribution to journalArticlepeer-review

Abstract

The reactions of unsaturated organic compounds with naked main-group ligands is an active area of coordination chemistry.1 The present contribution to this field involves the chemically induced reaction of a soluble ruthenium sulfide with acetylenes. This project has resulted in the characterization of the simplest ruthenium sulfido complex and a unique bonding mode for a 1,2-alkene disulfide (dithiolene) ligand.

Original languageEnglish (US)
Pages (from-to)3114-3115
Number of pages2
JournalJournal of the American Chemical Society
Volume108
Issue number11
DOIs
StatePublished - Jan 1 1986

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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