Synthesis of a New Type of Metal Dithiolene Complex via an Induced Reaction of Acetylenes with a Ruthenium Sulfide

Thomas Rauchfuss; Damian P.S. Rodgers; Scott R. Wilson

doi:10.1021/ja00271a056

Synthesis of a New Type of Metal Dithiolene Complex via an Induced Reaction of Acetylenes with a Ruthenium Sulfide

Thomas Rauchfuss, Damian P.S. Rodgers, Scott R. Wilson

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The reactions of unsaturated organic compounds with naked main-group ligands is an active area of coordination chemistry.¹ The present contribution to this field involves the chemically induced reaction of a soluble ruthenium sulfide with acetylenes. This project has resulted in the characterization of the simplest ruthenium sulfido complex and a unique bonding mode for a 1,2-alkene disulfide (dithiolene) ligand.

Original language	English (US)
Pages (from-to)	3114-3115
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	108
Issue number	11
DOIs	https://doi.org/10.1021/ja00271a056
State	Published - 1986

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja00271a056

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abstract = "The reactions of unsaturated organic compounds with naked main-group ligands is an active area of coordination chemistry.1 The present contribution to this field involves the chemically induced reaction of a soluble ruthenium sulfide with acetylenes. This project has resulted in the characterization of the simplest ruthenium sulfido complex and a unique bonding mode for a 1,2-alkene disulfide (dithiolene) ligand.",

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Synthesis of a New Type of Metal Dithiolene Complex via an Induced Reaction of Acetylenes with a Ruthenium Sulfide

Abstract

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