Synthesis and vibrational spectroscopy of 57Fe-labeled models of [NiFe] hydrogenase: first direct observation of a nickel–iron interaction

David Schilter, Vladimir Pelmenschikov, Hongxin Wang, Florian Meier, Leland B. Gee, Yoshitaka Yoda, Martin Kaupp, Thomas B. Rauchfuss, Stephen P. Cramer

Research output: Contribution to journalArticlepeer-review

Abstract

A new route to iron carbonyls has enabled synthesis of 57Fe-labeled [NiFe] hydrogenase mimic (OC)357Fe(pdt)Ni(dppe). Its study by nuclear resonance vibrational spectroscopy revealed Ni-57Fe vibrations, as confirmed by calculations. The modes are absent for [(OC)357Fe(pdt)Ni(dppe)]+, which lacks Ni-57Fe bonding, underscoring the utility of the analyses in identifying metal-metal interactions.

Original languageEnglish (US)
Pages (from-to)13469-13472
Number of pages4
JournalChemical Communications
Volume50
Issue number88
DOIs
StatePublished - Oct 9 2014

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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