Synthesis and S-centred reactivity of (C5Me5) 3Ru3S4+

Eric J. Houser; Harald Krautscheid; Thomas Rauchfuss; Scott R. Wilson

doi:10.1039/C39940001283

Synthesis and S-centred reactivity of (C₅Me₅) ₃Ru₃S₄⁺

Eric J. Houser, Harald Krautscheid, Thomas Rauchfuss, Scott R. Wilson

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Addition of (C₅Me₅)Ru⁺ to (C ₅Me₅)₂Ru₂S₄ affords (C₅Me₅)₃Ru₃S₄ ⁺; this cluster displays S-centred reactivity towards a range of electrophiles (H⁺, SO₂, Me⁺, Et⁺) to give adducts with solid-state structures containing Ru₃(μ ₃-S₂)(μ₃-S)(μ-SR) cores.

Original language	English (US)
Pages (from-to)	1283-1284
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/C39940001283
State	Published - 1994

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39940001283

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title = "Synthesis and S-centred reactivity of (C5Me5) 3Ru3S4+",

abstract = "Addition of (C5Me5)Ru+ to (C 5Me5)2Ru2S4 affords (C5Me5)3Ru3S4 +; this cluster displays S-centred reactivity towards a range of electrophiles (H+, SO2, Me+, Et+) to give adducts with solid-state structures containing Ru3(μ 3-S2)(μ3-S)(μ-SR) cores.",

author = "Houser, {Eric J.} and Harald Krautscheid and Thomas Rauchfuss and Wilson, {Scott R.}",

year = "1994",

doi = "10.1039/C39940001283",

language = "English (US)",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "11",

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AU - Krautscheid, Harald

AU - Rauchfuss, Thomas

AU - Wilson, Scott R.

PY - 1994

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AB - Addition of (C5Me5)Ru+ to (C 5Me5)2Ru2S4 affords (C5Me5)3Ru3S4 +; this cluster displays S-centred reactivity towards a range of electrophiles (H+, SO2, Me+, Et+) to give adducts with solid-state structures containing Ru3(μ 3-S2)(μ3-S)(μ-SR) cores.

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