Synthesis and reactivity of the osmium methylidene complex [(C5Me5)Os(=CH2)(dppm)][OTf]

Julia L. Brumaghim, Gregory S. Girolami

Research output: Contribution to journalArticlepeer-review

Abstract

Treatment of the hydride complex (C5Me5)Os(dppm)H, [dppm = bis(diphenylphosphino)methane] with 2 equivalents of methyl trifluoromethanesulfonate (MeOTf) affords the methylidene complex [(C5Me5)Os(=CH2)(dppm)][OTf]; the molecular structure and dynamic NMR behavior of this methylidene complex are described.

Original languageEnglish (US)
Pages (from-to)953-954
Number of pages2
JournalChemical Communications
Issue number11
DOIs
StatePublished - Jun 7 1999

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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