Synthesis and reactivity of dioxazirconacyclohexenes: Development of a zirconium-oxo-mediated alkyne-aldehyde coupling reaction

Gregory D. Kortman, Meghan J. Orr, Kami L. Hull

Research output: Contribution to journalArticle

Abstract

The zirconium-oxo-mediated coupling of an alkyne and an aldehyde for the synthesis of α,β-unsaturated ketones is presented. Each intermediate along the reaction pathway has been fully characterized, and the scope of the alkynes and aldehydes has been explored.

Original languageEnglish (US)
Pages (from-to)1013-1016
Number of pages4
JournalOrganometallics
Volume34
Issue number6
DOIs
StatePublished - Mar 23 2015

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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