Synthesis and reactivity of dioxazirconacyclohexenes: Development of a zirconium-oxo-mediated alkyne-aldehyde coupling reaction

Gregory D. Kortman; Meghan J. Orr; Kami L. Hull

doi:10.1021/om5008727

Synthesis and reactivity of dioxazirconacyclohexenes: Development of a zirconium-oxo-mediated alkyne-aldehyde coupling reaction

Gregory D. Kortman, Meghan J. Orr, Kami L. Hull

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The zirconium-oxo-mediated coupling of an alkyne and an aldehyde for the synthesis of α,β-unsaturated ketones is presented. Each intermediate along the reaction pathway has been fully characterized, and the scope of the alkynes and aldehydes has been explored.

Original language	English (US)
Pages (from-to)	1013-1016
Number of pages	4
Journal	Organometallics
Volume	34
Issue number	6
DOIs	https://doi.org/10.1021/om5008727
State	Published - Mar 23 2015

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om5008727

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title = "Synthesis and reactivity of dioxazirconacyclohexenes: Development of a zirconium-oxo-mediated alkyne-aldehyde coupling reaction",

abstract = "The zirconium-oxo-mediated coupling of an alkyne and an aldehyde for the synthesis of α,β-unsaturated ketones is presented. Each intermediate along the reaction pathway has been fully characterized, and the scope of the alkynes and aldehydes has been explored.",

author = "Kortman, {Gregory D.} and Orr, {Meghan J.} and Hull, {Kami L.}",

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T2 - Development of a zirconium-oxo-mediated alkyne-aldehyde coupling reaction

AU - Kortman, Gregory D.

AU - Orr, Meghan J.

AU - Hull, Kami L.

PY - 2015/3/23

Y1 - 2015/3/23

N2 - The zirconium-oxo-mediated coupling of an alkyne and an aldehyde for the synthesis of α,β-unsaturated ketones is presented. Each intermediate along the reaction pathway has been fully characterized, and the scope of the alkynes and aldehydes has been explored.

AB - The zirconium-oxo-mediated coupling of an alkyne and an aldehyde for the synthesis of α,β-unsaturated ketones is presented. Each intermediate along the reaction pathway has been fully characterized, and the scope of the alkynes and aldehydes has been explored.

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Synthesis and reactivity of dioxazirconacyclohexenes: Development of a zirconium-oxo-mediated alkyne-aldehyde coupling reaction

Abstract

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