Synthesis and crystal structure of 5,10,15,20-tetrakis(3,5-dinitrophenyl)porphyrin

P. Bhyrappa, K. S. Suslick

Research output: Contribution to journalArticlepeer-review

Abstract

The synthesis, characterization and crystal structure of the octanitro-substituted porphyrin 5,10,15,20-tetrakis(3,5-dinitrophenyl)porphyrin, H2T(3,5-DNP)P, are described. The solid state structure has two porphyrins in the unit cell with eight pyridine solvates and is made up from columnar arrays of the porphyrins. X-ray crystal structure data: monoclinic, space group P1 21/n1, a = 14.9996(9) Å, b = 8.2489(5) Å, c = 24.818(2) Å, α = 90°, β = 104.172(1)°, γ = 90°, V = 2977.3(3) Å3, dcalc = 1.440 g m-3, Z = 2.

Original languageEnglish (US)
Pages (from-to)391-396
Number of pages6
JournalJournal of Porphyrins and Phthalocyanines
Volume2
Issue number4-5
DOIs
StatePublished - 1998

Keywords

  • Nitroporphyrin
  • Structure determination
  • Synthesis
  • Tetraarylporphyrin
  • Tetraphenylporphyrin
  • X-ray crystallography

ASJC Scopus subject areas

  • Chemistry(all)

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