Synthesis and characterization of the hexagonal prismatic cage (THF⊂[PhB(CN)3]6[Cp*Rh]6)6+

Matthew L. Kuhlman; Haijun Yao; Thomas B. Rauchfuss

doi:10.1039/b401505c

Synthesis and characterization of the hexagonal prismatic cage (THF⊂[PhB(CN)₃]₆[Cp*Rh]₆)⁶⁺

Matthew L. Kuhlman
, Haijun Yao
, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Condensation of [Cp*Rh(CH₃NO₂) _n]²⁺ and the tricyanoborate [PhB(CN)₃] ^- affords the hexagonal bipyramidal cage {[PhB(CN)₃] ₆[Cp*Rh]₆}⁶⁺, demonstrating that tetrahedral tricyanide building blocks can lead to novel cage structures.

Original language	English (US)
Pages (from-to)	1370-1371
Number of pages	2
Journal	Chemical Communications
Volume	4
Issue number	12
DOIs	https://doi.org/10.1039/b401505c
State	Published - 2004

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Online availability

10.1039/b401505c

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Cite this

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title = "Synthesis and characterization of the hexagonal prismatic cage (THF⊂[PhB(CN)3]6[Cp*Rh]6)6+",

abstract = "Condensation of [Cp*Rh(CH3NO2) n]2+ and the tricyanoborate [PhB(CN)3] - affords the hexagonal bipyramidal cage \{[PhB(CN)3] 6[Cp*Rh]6\}6+, demonstrating that tetrahedral tricyanide building blocks can lead to novel cage structures.",

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AB - Condensation of [Cp*Rh(CH3NO2) n]2+ and the tricyanoborate [PhB(CN)3] - affords the hexagonal bipyramidal cage {[PhB(CN)3] 6[Cp*Rh]6}6+, demonstrating that tetrahedral tricyanide building blocks can lead to novel cage structures.

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