Abstract
A bidentate monoanionic NHC-CAryl ligand framework was synthesized, and a host of Ni(II) complexes were prepared. Addition of isocyanides to these complexes led to the formation of NHC-n2-iminoacyl nickel complexes. These complexes were characterized by a suite of spectroscopic techniques, including X-ray crystallography. The n2-iminoacyl was shown to be displaced from the nickel center with oxidant and could then be reattached with reductant.
Original language | English (US) |
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Pages (from-to) | 2987-2995 |
Number of pages | 9 |
Journal | Organometallics |
Volume | 36 |
Issue number | 15 |
DOIs | |
State | Published - Aug 14 2017 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry