Synthesis and Catalytic Activity of Mono(cyclopentadienyl)titanium(II) Complexes: X-ray Crystal Structures of CpTiX(Me2PCH2CH2PMe2)2 (X = Cl, Me, H) and Cp*Ti(η2-BH4)[η2-(Me2PCH2)3Si(t-Bu)]

Yujian You; Scott R. Wilson; Gregory S. Girolami

doi:10.1021/om00024a003

Synthesis and Catalytic Activity of Mono(cyclopentadienyl)titanium(II) Complexes: X-ray Crystal Structures of CpTiX(Me₂PCH₂CH₂PMe₂)₂ (X = Cl, Me, H) and Cp*Ti(η²-BH₄)[η²-(Me₂PCH₂)₃Si(t-Bu)]

Yujian You
, Scott R. Wilson
, Gregory S. Girolami

Research output: Contribution to journal › Article › peer-review

Abstract

New mono(cyclopentadienyl)- and mono(pentamethylcyclopentadienyl) titanium(II) complexes have been prepared that are active for the oligomerization of ethylene to the dimer 1-butene and the trimers 2-ethyl-1-butene and 3-methyl-1-pentene. The mechanism of the catalysis is proposed to involve titanacyclopentane intermediates.

Original language	English (US)
Pages (from-to)	4655-4657
Number of pages	3
Journal	Organometallics
Volume	13
Issue number	12
DOIs	https://doi.org/10.1021/om00024a003
State	Published - Dec 1 1994

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00024a003

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Synthesis and Catalytic Activity of Mono(cyclopentadienyl)titanium(II) Complexes: X-ray Crystal Structures of CpTiX(Me₂PCH₂CH₂PMe₂)₂ (X = Cl, Me, H) and Cp*Ti(η²-BH₄)[η²-(Me₂PCH₂)₃Si(t-Bu)]. / You, Yujian; Wilson, Scott R.; Girolami, Gregory S.
In: Organometallics, Vol. 13, No. 12, 01.12.1994, p. 4655-4657.

Research output: Contribution to journal › Article › peer-review

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abstract = "New mono(cyclopentadienyl)- and mono(pentamethylcyclopentadienyl) titanium(II) complexes have been prepared that are active for the oligomerization of ethylene to the dimer 1-butene and the trimers 2-ethyl-1-butene and 3-methyl-1-pentene. The mechanism of the catalysis is proposed to involve titanacyclopentane intermediates.",

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