Synthesen und kristallstrukturen neuer selenidoverbrückter ruthenium-clusterverbindungen

Markus Wunder; Thomas B. Rauchfuss; Dieter Fenske

doi:10.1002/zaac.200400204

Synthesen und kristallstrukturen neuer selenidoverbrückter ruthenium-clusterverbindungen

Translated title of the contribution: Syntheses and crystal structures of new selenido-bridged ruthenium clusters

Markus Wunder, Thomas B. Rauchfuss, Dieter Fenske

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of Se(SiMe₃)₂ with [RuCl ₂(PPh₃)₃], or a mixture of [RuCl ₂(PPh₃)₃] and alkylphosphines leads to the formation of selenido-bridged ruthenium clusters. In this publication the compounds [Ru₆Se₈(PPh₃)₆] (1), [Ru₆Se₈(PEt₃)₆] (2) und[Ru ₆Se₈-(PⁿPr₃)₆] (3) are described. The compounds 1-3 contain Ru₆¹⁶⁺ cluster cores with Ru²⁺ and Ru³⁺ centers. The structures of these compounds were elucidated by single crystal X-ray structural analyses.

Translated title of the contribution	Syntheses and crystal structures of new selenido-bridged ruthenium clusters
Original language	German
Pages (from-to)	1578-1580
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	630
Issue number	11
DOIs	https://doi.org/10.1002/zaac.200400204
State	Published - Oct 12 2004
Externally published	Yes

Keywords

Cluster compounds
Ruthenium
Selenido-bridged compounds

ASJC Scopus subject areas

Inorganic Chemistry

Online availability

10.1002/zaac.200400204

Library availability

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abstract = "The reaction of Se(SiMe3)2 with [RuCl 2(PPh3)3], or a mixture of [RuCl 2(PPh3)3] and alkylphosphines leads to the formation of selenido-bridged ruthenium clusters. In this publication the compounds [Ru6Se8(PPh3)6] (1), [Ru6Se8(PEt3)6] (2) und[Ru 6Se8-(PnPr3)6] (3) are described. The compounds 1-3 contain Ru616+ cluster cores with Ru2+ and Ru3+ centers. The structures of these compounds were elucidated by single crystal X-ray structural analyses.",

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AU - Wunder, Markus

AU - Rauchfuss, Thomas B.

AU - Fenske, Dieter

PY - 2004/10/12

Y1 - 2004/10/12

N2 - The reaction of Se(SiMe3)2 with [RuCl 2(PPh3)3], or a mixture of [RuCl 2(PPh3)3] and alkylphosphines leads to the formation of selenido-bridged ruthenium clusters. In this publication the compounds [Ru6Se8(PPh3)6] (1), [Ru6Se8(PEt3)6] (2) und[Ru 6Se8-(PnPr3)6] (3) are described. The compounds 1-3 contain Ru616+ cluster cores with Ru2+ and Ru3+ centers. The structures of these compounds were elucidated by single crystal X-ray structural analyses.

AB - The reaction of Se(SiMe3)2 with [RuCl 2(PPh3)3], or a mixture of [RuCl 2(PPh3)3] and alkylphosphines leads to the formation of selenido-bridged ruthenium clusters. In this publication the compounds [Ru6Se8(PPh3)6] (1), [Ru6Se8(PEt3)6] (2) und[Ru 6Se8-(PnPr3)6] (3) are described. The compounds 1-3 contain Ru616+ cluster cores with Ru2+ and Ru3+ centers. The structures of these compounds were elucidated by single crystal X-ray structural analyses.

KW - Cluster compounds

KW - Ruthenium

KW - Selenido-bridged compounds

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Synthesen und kristallstrukturen neuer selenidoverbrückter ruthenium-clusterverbindungen

Abstract

Keywords

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