Synthesen und kristallstrukturen neuer selenidoverbrückter ruthenium-clusterverbindungen

Translated title of the contribution: Syntheses and crystal structures of new selenido-bridged ruthenium clusters

Markus Wunder, Thomas B. Rauchfuss, Dieter Fenske

Research output: Contribution to journalArticlepeer-review

Abstract

The reaction of Se(SiMe3)2 with [RuCl 2(PPh3)3], or a mixture of [RuCl 2(PPh3)3] and alkylphosphines leads to the formation of selenido-bridged ruthenium clusters. In this publication the compounds [Ru6Se8(PPh3)6] (1), [Ru6Se8(PEt3)6] (2) und[Ru 6Se8-(PnPr3)6] (3) are described. The compounds 1-3 contain Ru616+ cluster cores with Ru2+ and Ru3+ centers. The structures of these compounds were elucidated by single crystal X-ray structural analyses.

Translated title of the contributionSyntheses and crystal structures of new selenido-bridged ruthenium clusters
Original languageGerman
Pages (from-to)1578-1580
Number of pages3
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume630
Issue number11
DOIs
StatePublished - 2004
Externally publishedYes

Keywords

  • Cluster compounds
  • Ruthenium
  • Selenido-bridged compounds

ASJC Scopus subject areas

  • Inorganic Chemistry

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