TY - JOUR
T1 - Switching the selectivity of a polyglycerol dendrimer monomolecularly imprinted with d-(-)-fructose
AU - Hashidzume, Akihito
AU - Zimmerman, Steven C.
N1 - Funding Information:
Funding of this work by the National Institutes of Health is gratefully acknowledged. A.H. acknowledges Osaka University and the Ministry of Education, Culture, Sports, Science, and Technology, Japan for the Overseas Advanced Educational Research Practice Support Program ‘University Education Internationalization Promotion Program’.
PY - 2009/5/13
Y1 - 2009/5/13
N2 - A polyglycerol dendrimer monomolecularly imprinted with d-(-)-fructose (Fru) was synthesized. The dendrimer formed adducts with several monosaccharides, Fru, d-(+)-galactose, d-(+)-glucose, d-(+)-mannose, and methyl-α-d-mannopyranoside (MMan), by removal of four water molecules. The dendrimer preferred Fru in the absence of N,N,N′,N′-tetramethyldiaminomethane (TMDAM), whereas it preferred MMan in the presence of TMDAM.
AB - A polyglycerol dendrimer monomolecularly imprinted with d-(-)-fructose (Fru) was synthesized. The dendrimer formed adducts with several monosaccharides, Fru, d-(+)-galactose, d-(+)-glucose, d-(+)-mannose, and methyl-α-d-mannopyranoside (MMan), by removal of four water molecules. The dendrimer preferred Fru in the absence of N,N,N′,N′-tetramethyldiaminomethane (TMDAM), whereas it preferred MMan in the presence of TMDAM.
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U2 - 10.1016/j.tetlet.2009.02.168
DO - 10.1016/j.tetlet.2009.02.168
M3 - Article
AN - SCOPUS:62749086335
SN - 0040-4039
VL - 50
SP - 2204
EP - 2207
JO - Tetrahedron Letters
JF - Tetrahedron Letters
IS - 19
ER -