Switching the selectivity of a polyglycerol dendrimer monomolecularly imprinted with d-(-)-fructose

Akihito Hashidzume, Steven C. Zimmerman

Research output: Contribution to journalArticlepeer-review

Abstract

A polyglycerol dendrimer monomolecularly imprinted with d-(-)-fructose (Fru) was synthesized. The dendrimer formed adducts with several monosaccharides, Fru, d-(+)-galactose, d-(+)-glucose, d-(+)-mannose, and methyl-α-d-mannopyranoside (MMan), by removal of four water molecules. The dendrimer preferred Fru in the absence of N,N,N′,N′-tetramethyldiaminomethane (TMDAM), whereas it preferred MMan in the presence of TMDAM.

Original languageEnglish (US)
Pages (from-to)2204-2207
Number of pages4
JournalTetrahedron Letters
Volume50
Issue number19
DOIs
StatePublished - May 13 2009

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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