Surface-initiated ring-opening metathesis polymerization on Si/SiO2

Namyong Y. Kim; Noo Li Jeon; Insung S. Choi; Seiichi Takami; Yoshiko Harada; Krista R. Finnie; Gregory S. Girolami; Ralph G. Nuzzo; George M. Whitesides; Paul E. Laibinis

doi:10.1021/ma000046c

Surface-initiated ring-opening metathesis polymerization on Si/SiO₂

Namyong Y. Kim, Noo Li Jeon, Insung S. Choi, Seiichi Takami, Yoshiko Harada, Krista R. Finnie, Gregory S. Girolami, Ralph G. Nuzzo, George M. Whitesides, Paul E. Laibinis

Research output: Contribution to journal › Article › peer-review

Abstract

A method for growing thin polymer films from the surface of a silicon wafer bearing a native oxide (Si/SiO₂) by ring-opening metathesis polymerization (ROMP) is described. The norbornene-derived polymer films were prepared with a wide range of thicknesses up to 1 μm and with a control over the chemical composition of the film perpendicular to the surface. It was observed that surface-initiated polymerization using ROMP can be used to grow covalently attached norbornene-based polymer films from an oxide surface by solution phase procedures.

Original language	English (US)
Pages (from-to)	2793-2795
Number of pages	3
Journal	Macromolecules
Volume	33
Issue number	8
DOIs	https://doi.org/10.1021/ma000046c
State	Published - Apr 18 2000

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

Online availability

10.1021/ma000046c

Library availability

Discover UIUC Full Text

Cite this

@article{ab99276308344692843f4024e8cf8b1a,

title = "Surface-initiated ring-opening metathesis polymerization on Si/SiO2",

abstract = "A method for growing thin polymer films from the surface of a silicon wafer bearing a native oxide (Si/SiO2) by ring-opening metathesis polymerization (ROMP) is described. The norbornene-derived polymer films were prepared with a wide range of thicknesses up to 1 μm and with a control over the chemical composition of the film perpendicular to the surface. It was observed that surface-initiated polymerization using ROMP can be used to grow covalently attached norbornene-based polymer films from an oxide surface by solution phase procedures.",

author = "Kim, {Namyong Y.} and Jeon, {Noo Li} and Choi, {Insung S.} and Seiichi Takami and Yoshiko Harada and Finnie, {Krista R.} and Girolami, {Gregory S.} and Nuzzo, {Ralph G.} and Whitesides, {George M.} and Laibinis, {Paul E.}",

year = "2000",

month = apr,

day = "18",

doi = "10.1021/ma000046c",

language = "English (US)",

volume = "33",

pages = "2793--2795",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Surface-initiated ring-opening metathesis polymerization on Si/SiO2

AU - Kim, Namyong Y.

AU - Jeon, Noo Li

AU - Choi, Insung S.

AU - Takami, Seiichi

AU - Harada, Yoshiko

AU - Finnie, Krista R.

AU - Girolami, Gregory S.

AU - Nuzzo, Ralph G.

AU - Whitesides, George M.

AU - Laibinis, Paul E.

PY - 2000/4/18

Y1 - 2000/4/18

N2 - A method for growing thin polymer films from the surface of a silicon wafer bearing a native oxide (Si/SiO2) by ring-opening metathesis polymerization (ROMP) is described. The norbornene-derived polymer films were prepared with a wide range of thicknesses up to 1 μm and with a control over the chemical composition of the film perpendicular to the surface. It was observed that surface-initiated polymerization using ROMP can be used to grow covalently attached norbornene-based polymer films from an oxide surface by solution phase procedures.

AB - A method for growing thin polymer films from the surface of a silicon wafer bearing a native oxide (Si/SiO2) by ring-opening metathesis polymerization (ROMP) is described. The norbornene-derived polymer films were prepared with a wide range of thicknesses up to 1 μm and with a control over the chemical composition of the film perpendicular to the surface. It was observed that surface-initiated polymerization using ROMP can be used to grow covalently attached norbornene-based polymer films from an oxide surface by solution phase procedures.

UR - http://www.scopus.com/inward/record.url?scp=0033743752&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033743752&partnerID=8YFLogxK

U2 - 10.1021/ma000046c

DO - 10.1021/ma000046c

M3 - Article

AN - SCOPUS:0033743752

SN - 0024-9297

VL - 33

SP - 2793

EP - 2795

JO - Macromolecules

JF - Macromolecules

IS - 8

ER -