Abstract
UV-induced matrix cross-linking is the method of choice to form polymer-dispersed liquid crystals (PDLCs). In this paper, real-time FTIR spectroscopy is applied to study the curing of a model system - a thiolene-chemistry-based prepolymer (NOA65) and its mixtures with liquid crystals. Curing reactions of NOA65 were examined as a function of the film thickness, temperature, and liquid-crystal content. While there was little dependence of the curing behavior on the thickness of the film, the effect of temperature was strong. Curing rates exhibit a maximum around 325 K, while conversions reach a plateau about 20 K higher. The effect of liquid-crystal addition reveals a depression in the conversion. However, compared to the neat matrix, the final conversion was found to be significantly lower only for phase-separating concentrations. The rate of reaction decreased, and the induction period for the onset of polymerizing reactions increased with increasing liquid-crystal concentration. Real-time FTIR spectroscopy is shown to be a viable tool to monitor PDLC formation to optimize curing conditions and characterize the chemical state of components. This provides a basis to allow the morphological structure to be related to observed properties of the film.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 8982-8988 |
| Number of pages | 7 |
| Journal | Macromolecules |
| Volume | 32 |
| Issue number | 26 |
| DOIs | |
| State | Published - Dec 28 1999 |
| Externally published | Yes |
ASJC Scopus subject areas
- Materials Chemistry
- Polymers and Plastics
- Inorganic Chemistry
- Organic Chemistry