Studying polymer-dispersed liquid-crystal formation by FTIR spectroscopy. 1. Monitoring curing reactions

Rohit Bhargava, Shi Qing Wang, Jack L. Koenig

Research output: Contribution to journalArticle

Abstract

UV-induced matrix cross-linking is the method of choice to form polymer-dispersed liquid crystals (PDLCs). In this paper, real-time FTIR spectroscopy is applied to study the curing of a model system - a thiolene-chemistry-based prepolymer (NOA65) and its mixtures with liquid crystals. Curing reactions of NOA65 were examined as a function of the film thickness, temperature, and liquid-crystal content. While there was little dependence of the curing behavior on the thickness of the film, the effect of temperature was strong. Curing rates exhibit a maximum around 325 K, while conversions reach a plateau about 20 K higher. The effect of liquid-crystal addition reveals a depression in the conversion. However, compared to the neat matrix, the final conversion was found to be significantly lower only for phase-separating concentrations. The rate of reaction decreased, and the induction period for the onset of polymerizing reactions increased with increasing liquid-crystal concentration. Real-time FTIR spectroscopy is shown to be a viable tool to monitor PDLC formation to optimize curing conditions and characterize the chemical state of components. This provides a basis to allow the morphological structure to be related to observed properties of the film.

Original languageEnglish (US)
Pages (from-to)8982-8988
Number of pages7
JournalMacromolecules
Volume32
Issue number26
DOIs
StatePublished - Dec 28 1999
Externally publishedYes

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Liquid crystal polymers
Liquid Crystals
Curing
Liquid crystals
Spectroscopy
Monitoring
Film thickness
Temperature

ASJC Scopus subject areas

  • Materials Chemistry

Cite this

Studying polymer-dispersed liquid-crystal formation by FTIR spectroscopy. 1. Monitoring curing reactions. / Bhargava, Rohit; Wang, Shi Qing; Koenig, Jack L.

In: Macromolecules, Vol. 32, No. 26, 28.12.1999, p. 8982-8988.

Research output: Contribution to journalArticle

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