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Studies on the Mechanism and Origin of Stereoselective Opening of Chiral Dioxane Acetals
Scott E. Denmark
, Neil G. Almstead
Chemistry
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peer-review
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Dive into the research topics of 'Studies on the Mechanism and Origin of Stereoselective Opening of Chiral Dioxane Acetals'. Together they form a unique fingerprint.
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Keyphrases
Acetal
100%
Stereoselectivity
100%
Dioxane
100%
Ion Pairs
50%
Stoichiometry
33%
Mechanistic Schemes
33%
Lewis Acids
16%
Substitution Reaction
16%
Acid Type
16%
Stereochemical Hypothesis
16%
Bond Breaking
16%
Substitution Process
16%
Experimental Variables
16%
Structural Variables
16%
Trisubstituted
16%
Stereoselection
16%
Oxocarbenium Ion
16%
Enol Ethers
16%
1,3-dioxane
16%
Allylation
16%
Allylsilane
16%
Cyclic Acetals
16%
Limiting Mechanism
16%
Meso-2
16%
Allyltrimethylsilane
16%
Chemistry
Acetal
100%
Dioxane
100%
Ion Pair
50%
Reaction Stoichiometry
33%
Structure
16%
Lewis Acid
16%
Substitution Reaction
16%
Allylation
16%
Enol Ether
16%
1,3-dioxane
16%
Allylsilane
16%
Cyclic Acetal
16%