Abstract
Thirty-five allyl vinyl ethers bearing an arylsulfonyl anion-stabilizing group have been prepared by addition of allylic alkoxides to (arylsulfonyl)allenes. The allyl vinyl ethers are produced as either β,γ-unsaturated or α,β-unsaturated sulfones depending upon the substitution pattern of the allene and the reaction conditions. A wide variety of substitution patterns are available by using this method. Factors that control the position and stereochemistry of the vinyl ether double bond are discussed.
Original language | English (US) |
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Pages (from-to) | 4031-4042 |
Number of pages | 12 |
Journal | Journal of Organic Chemistry |
Volume | 52 |
Issue number | 18 |
DOIs | |
State | Published - Sep 1 1987 |
ASJC Scopus subject areas
- Organic Chemistry