Structure of the Si(011)-(16 × 2) surface and hydrogen desorption kinetics investigated using temperature-programmed desorption

H. Kim; N. Taylor; T. Spila; G. Glass; S. Y. Park; I. E. Greene; J. R. Abelson

doi:10.1016/S0039-6028(96)01587-7

Structure of the Si(011)-(16 × 2) surface and hydrogen desorption kinetics investigated using temperature-programmed desorption

H. Kim, N. Taylor, T. Spila, G. Glass, S. Y. Park, I. E. Greene, J. R. Abelson

Research output: Contribution to journal › Article › peer-review

Abstract

D₂ temperature-programmed desorption (TPD) was used to probe the structure of the Si(011)-(16 × 2) surface. Deuterium was adsorbed at 200°C to coverages θ_D ranging up to complete saturation (approximately 1.1 ML) and the sample heated at 5 Cs^-1. TPD spectra exhibited three second-order desorption peaks labelled β₂, β*₁ and β₁, centered at 430, 520 and 550°C. Of the proposed models for the Si(011)-(16 × 2) reconstruction, the present TPD results as a function of θ_D provide support for the adatom/dimer model with the β₂ peak assigned to D₂ desorption from the dihydride phase, while the β*₁ and β₁ peaks arise from adatom and surface-atom monohydride phases.

Original language	English (US)
Pages (from-to)	L496-L500
Journal	Surface Science
Volume	380
Issue number	2-3
DOIs	https://doi.org/10.1016/S0039-6028(96)01587-7
State	Published - May 15 1997

Keywords

Adatoms
Deuterium
Silicon
Surface relaxation and reconstruction
Thermal desorption spectroscopy

ASJC Scopus subject areas

Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films
Materials Chemistry

Online availability

10.1016/S0039-6028(96)01587-7

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title = "Structure of the Si(011)-(16 × 2) surface and hydrogen desorption kinetics investigated using temperature-programmed desorption",

abstract = "D2 temperature-programmed desorption (TPD) was used to probe the structure of the Si(011)-(16 × 2) surface. Deuterium was adsorbed at 200°C to coverages θD ranging up to complete saturation (approximately 1.1 ML) and the sample heated at 5 Cs-1. TPD spectra exhibited three second-order desorption peaks labelled β2, β*1 and β1, centered at 430, 520 and 550°C. Of the proposed models for the Si(011)-(16 × 2) reconstruction, the present TPD results as a function of θD provide support for the adatom/dimer model with the β2 peak assigned to D2 desorption from the dihydride phase, while the β*1 and β1 peaks arise from adatom and surface-atom monohydride phases.",

keywords = "Adatoms, Deuterium, Silicon, Surface relaxation and reconstruction, Thermal desorption spectroscopy",

author = "H. Kim and N. Taylor and T. Spila and G. Glass and Park, {S. Y.} and Greene, {I. E.} and Abelson, {J. R.}",

year = "1997",

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doi = "10.1016/S0039-6028(96)01587-7",

language = "English (US)",

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TY - JOUR

T1 - Structure of the Si(011)-(16 × 2) surface and hydrogen desorption kinetics investigated using temperature-programmed desorption

AU - Kim, H.

AU - Taylor, N.

AU - Spila, T.

AU - Glass, G.

AU - Park, S. Y.

AU - Greene, I. E.

AU - Abelson, J. R.

PY - 1997/5/15

Y1 - 1997/5/15

N2 - D2 temperature-programmed desorption (TPD) was used to probe the structure of the Si(011)-(16 × 2) surface. Deuterium was adsorbed at 200°C to coverages θD ranging up to complete saturation (approximately 1.1 ML) and the sample heated at 5 Cs-1. TPD spectra exhibited three second-order desorption peaks labelled β2, β*1 and β1, centered at 430, 520 and 550°C. Of the proposed models for the Si(011)-(16 × 2) reconstruction, the present TPD results as a function of θD provide support for the adatom/dimer model with the β2 peak assigned to D2 desorption from the dihydride phase, while the β*1 and β1 peaks arise from adatom and surface-atom monohydride phases.

AB - D2 temperature-programmed desorption (TPD) was used to probe the structure of the Si(011)-(16 × 2) surface. Deuterium was adsorbed at 200°C to coverages θD ranging up to complete saturation (approximately 1.1 ML) and the sample heated at 5 Cs-1. TPD spectra exhibited three second-order desorption peaks labelled β2, β*1 and β1, centered at 430, 520 and 550°C. Of the proposed models for the Si(011)-(16 × 2) reconstruction, the present TPD results as a function of θD provide support for the adatom/dimer model with the β2 peak assigned to D2 desorption from the dihydride phase, while the β*1 and β1 peaks arise from adatom and surface-atom monohydride phases.

KW - Adatoms

KW - Deuterium

KW - Silicon

KW - Surface relaxation and reconstruction

KW - Thermal desorption spectroscopy

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UR - http://www.scopus.com/inward/citedby.url?scp=0031142925&partnerID=8YFLogxK

U2 - 10.1016/S0039-6028(96)01587-7

DO - 10.1016/S0039-6028(96)01587-7

M3 - Article

AN - SCOPUS:0031142925

SN - 0039-6028

VL - 380

SP - L496-L500

JO - Surface Science

JF - Surface Science

IS - 2-3

ER -

Structure of the Si(011)-(16 × 2) surface and hydrogen desorption kinetics investigated using temperature-programmed desorption

Abstract

Keywords

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