Structure and Spectroscopy of Copper-Dioxygen Complexes

Liviu M. Mirica; Xavier Ottenwaelder; T. Daniel P. Stack

doi:10.1021/cr020632z

Structure and Spectroscopy of Copper-Dioxygen Complexes

Liviu M. Mirica, Xavier Ottenwaelder, T. Daniel P. Stack

Research output: Contribution to journal › Review article › peer-review

Abstract

The structures and spectroscopic properties of well-characterized copper-dioxygen complexes were analyzed. The ligand attributes that create O ₂-reactive Cu(I) complexes and lead to specific types of Cu/O ₂ species were discussed. It was shown that prevalent formation of dimeric Cu/O ₂ complexes in homogeneous solutions is consistent with the thermodynamic trends of O ₂ reduction. The results show that most Cu/O ₂ reactions generate a thermodynamic rather than a kinetic Cu/O ₂ product.

Original language	English (US)
Pages (from-to)	1013-1045
Number of pages	33
Journal	Chemical reviews
Volume	104
Issue number	2
DOIs	https://doi.org/10.1021/cr020632z
State	Published - Feb 2004
Externally published	Yes

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Chemistry(all)

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10.1021/cr020632z

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title = "Structure and Spectroscopy of Copper-Dioxygen Complexes",

abstract = "The structures and spectroscopic properties of well-characterized copper-dioxygen complexes were analyzed. The ligand attributes that create O 2-reactive Cu(I) complexes and lead to specific types of Cu/O 2 species were discussed. It was shown that prevalent formation of dimeric Cu/O 2 complexes in homogeneous solutions is consistent with the thermodynamic trends of O 2 reduction. The results show that most Cu/O 2 reactions generate a thermodynamic rather than a kinetic Cu/O 2 product.",

author = "Mirica, {Liviu M.} and Xavier Ottenwaelder and Stack, {T. Daniel P.}",

year = "2004",

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publisher = "American Chemical Society",

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T1 - Structure and Spectroscopy of Copper-Dioxygen Complexes

AU - Mirica, Liviu M.

AU - Ottenwaelder, Xavier

AU - Stack, T. Daniel P.

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Y1 - 2004/2

N2 - The structures and spectroscopic properties of well-characterized copper-dioxygen complexes were analyzed. The ligand attributes that create O 2-reactive Cu(I) complexes and lead to specific types of Cu/O 2 species were discussed. It was shown that prevalent formation of dimeric Cu/O 2 complexes in homogeneous solutions is consistent with the thermodynamic trends of O 2 reduction. The results show that most Cu/O 2 reactions generate a thermodynamic rather than a kinetic Cu/O 2 product.

AB - The structures and spectroscopic properties of well-characterized copper-dioxygen complexes were analyzed. The ligand attributes that create O 2-reactive Cu(I) complexes and lead to specific types of Cu/O 2 species were discussed. It was shown that prevalent formation of dimeric Cu/O 2 complexes in homogeneous solutions is consistent with the thermodynamic trends of O 2 reduction. The results show that most Cu/O 2 reactions generate a thermodynamic rather than a kinetic Cu/O 2 product.

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ER -

Structure and Spectroscopy of Copper-Dioxygen Complexes

Abstract

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