Stereoselective Alkylations of Chiral, Phosphorus-Stabilized Benzylic Carbanions

Scott E Denmark, Roberta L. Dorow

Research output: Contribution to journalArticlepeer-review

Abstract

: A series of 6-substituted 2-benzyl-3-tert-bu-tyl-1,3,2-oxazaphosphorinanes was prepared in racemic and enantiomerically pure form. The diastereoselectivity of alkylation of the derived anions was examined as a function of ring substitution pattern, base, solvent, electrophile, and enantiomeric composition.

Original languageEnglish (US)
Pages (from-to)5926-5928
Number of pages3
JournalJournal of Organic Chemistry
Volume55
Issue number24
DOIs
StatePublished - Nov 1990

ASJC Scopus subject areas

  • Organic Chemistry

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