Stereochemistry of electrophilic attack at 34e- dimetallic complexes: The case of diiron dithiolato carbonyls + MeS+

Matthew T. Olsen; Danielle L. Gray; Thomas B. Rauchfuss; Luca De Gioia; Giuseppe Zampella

doi:10.1039/c1cc10858a

Stereochemistry of electrophilic attack at 34e^- dimetallic complexes: The case of diiron dithiolato carbonyls + MeS⁺

Matthew T. Olsen, Danielle L. Gray, Thomas B. Rauchfuss, Luca De Gioia, Giuseppe Zampella

Research output: Contribution to journal › Article › peer-review

Abstract

Experimental and computational experiments show that the electrophile MeS⁺ attacks a single Fe center in Fe₂(propanedithiolate) (CO)₄(PMe₃)₂ followed by isomerization of this terminal thiolato complex to the corresponding μ-SMe derivative.

Original language	English (US)
Pages (from-to)	6554-6556
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	23
DOIs	https://doi.org/10.1039/c1cc10858a
State	Published - Jun 21 2011

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c1cc10858a

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title = "Stereochemistry of electrophilic attack at 34e- dimetallic complexes: The case of diiron dithiolato carbonyls + MeS+",

abstract = "Experimental and computational experiments show that the electrophile MeS+ attacks a single Fe center in Fe2(propanedithiolate) (CO)4(PMe3)2 followed by isomerization of this terminal thiolato complex to the corresponding μ-SMe derivative.",

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