Stereochemical Studies on the Addition of Allylsilanes to Aldehydes. The SE′ Component

Scott E. Denmark; Neil G. Almstead

doi:10.1021/jo00097a008

Stereochemical Studies on the Addition of Allylsilanes to Aldehydes. The S_E′ Component

Scott E. Denmark, Neil G. Almstead

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Compounds (l)-1 and (u)-1 have revealed both the position of the silicon electrofuge and the relative orientation of the double bonds in the allylmetal–aldehyde addition. Cyclization was found to proceed with high selectivity via an anti S_E′ pathway regardless of the proximal/distal ratio.

Original language	English (US)
Pages (from-to)	5130-5132
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	59
Issue number	18
DOIs	https://doi.org/10.1021/jo00097a008
State	Published - Sep 1 1994

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo00097a008

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title = "Stereochemical Studies on the Addition of Allylsilanes to Aldehydes. The SE′ Component",

abstract = "Compounds (l)-1 and (u)-1 have revealed both the position of the silicon electrofuge and the relative orientation of the double bonds in the allylmetal–aldehyde addition. Cyclization was found to proceed with high selectivity via an anti SE′ pathway regardless of the proximal/distal ratio.",

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