Stereochemical studies of the opening of chloro vinyl epoxides: Cyclic chloronium ions as intermediates

Andrej Shemet, David Sarlah, Erick M. Carreira

Research output: Contribution to journalArticlepeer-review

Abstract

A systematic study of the opening of a collection of chlorinated vinyl epoxides is reported, which includes experiments that implicate both five- and four-membered chloronium ions as plausible intermediates in this type of epoxide opening reaction.

Original languageEnglish (US)
Pages (from-to)1878-1881
Number of pages4
JournalOrganic Letters
Volume17
Issue number8
DOIs
StatePublished - Apr 17 2015
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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