Stabilization of the hindered urea bond through de-tert-butylation

Yingfeng Yang; Hanze Ying; Yunchao Jia; Yingying Chen; Jianjun Cheng

doi:10.1039/d1cc00715g

Stabilization of the hindered urea bond through de-tert-butylation

Yingfeng Yang, Hanze Ying, Yunchao Jia, Yingying Chen, Jianjun Cheng

Research output: Contribution to journal › Article › peer-review

Abstract

We report the discovery of an acid-assisted de-tert-butylation reaction that can instantly “turn off” the dynamicity of hindered urea bonds (HUBs) and thus broaden their applications. The reaction is demonstrated to be widely applicable to different hindered urea substrates, leading to improved chemical stabilities and mechanical properties of HUB-containing materials.

Original language	English (US)
Pages (from-to)	3812-3815
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	31
Early online date	2021
DOIs	https://doi.org/10.1039/d1cc00715g
State	Published - Apr 21 2021

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

Online availability

10.1039/d1cc00715g

Library availability

Discover UIUC Full Text

Cite this

@article{3cedf0871b5a4a09af14cc7295e6b3cb,

title = "Stabilization of the hindered urea bond through de-tert-butylation",

abstract = "We report the discovery of an acid-assisted de-tert-butylation reaction that can instantly “turn off” the dynamicity of hindered urea bonds (HUBs) and thus broaden their applications. The reaction is demonstrated to be widely applicable to different hindered urea substrates, leading to improved chemical stabilities and mechanical properties of HUB-containing materials.",

author = "Yingfeng Yang and Hanze Ying and Yunchao Jia and Yingying Chen and Jianjun Cheng",

note = "This work was supported by the United States National Science Foundation (NSF CHE 17-09820) and American Chemical Society Petroleum Research Fund (58671-ND7).",

year = "2021",

month = apr,

day = "21",

doi = "10.1039/d1cc00715g",

language = "English (US)",

volume = "57",

pages = "3812--3815",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "31",

}

TY - JOUR

T1 - Stabilization of the hindered urea bond through de-tert-butylation

AU - Yang, Yingfeng

AU - Ying, Hanze

AU - Jia, Yunchao

AU - Chen, Yingying

AU - Cheng, Jianjun

N1 - This work was supported by the United States National Science Foundation (NSF CHE 17-09820) and American Chemical Society Petroleum Research Fund (58671-ND7).

PY - 2021/4/21

Y1 - 2021/4/21

N2 - We report the discovery of an acid-assisted de-tert-butylation reaction that can instantly “turn off” the dynamicity of hindered urea bonds (HUBs) and thus broaden their applications. The reaction is demonstrated to be widely applicable to different hindered urea substrates, leading to improved chemical stabilities and mechanical properties of HUB-containing materials.

AB - We report the discovery of an acid-assisted de-tert-butylation reaction that can instantly “turn off” the dynamicity of hindered urea bonds (HUBs) and thus broaden their applications. The reaction is demonstrated to be widely applicable to different hindered urea substrates, leading to improved chemical stabilities and mechanical properties of HUB-containing materials.

UR - http://www.scopus.com/inward/record.url?scp=85104181524&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85104181524&partnerID=8YFLogxK

U2 - 10.1039/d1cc00715g

DO - 10.1039/d1cc00715g

M3 - Article

C2 - 33876129

AN - SCOPUS:85104181524

SN - 1359-7345

VL - 57

SP - 3812

EP - 3815

JO - Chemical Communications

JF - Chemical Communications

IS - 31

ER -

Stabilization of the hindered urea bond through de-tert-butylation

Abstract

ASJC Scopus subject areas

Online availability

Library availability

Related links

Fingerprint

Cite this