Spectroscopic characterizations of the 3Σg + and 3Πg components of nf complexes of Ne2 with n=4-6

S. B. Kim; D. J. Kane; J. G. Eden; Marshall L. Ginter

doi:10.1063/1.460388

Spectroscopic characterizations of the ³Σ_g ⁺ and ³Π_g components of nf complexes of Ne₂ with n=4-6

S. B. Kim, D. J. Kane, J. G. Eden, Marshall L. Ginter

Electrical and Computer Engineering

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Abstract

Rotationally resolved, laser-induced fluorescence spectra for the transitions nf (³Σ_g⁺,³Π _g) ←a ³Σ_u⁺ (n = 4-6) in Ne₂ are presented and analyzed. The rotational structures of the upper states are found to be strongly l-uncoupled. Effective rotational constants for the a ³Σ_u⁺, nfσ ³Σ_u⁺, and nfπ ³ _u^± states with n = 4-6 are reported and the structures of the nf complexes discussed.

Original language	English (US)
Pages (from-to)	145-152
Number of pages	8
Journal	The Journal of Chemical Physics
Volume	94
Issue number	1
DOIs	https://doi.org/10.1063/1.460388
State	Published - 1991

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.460388

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abstract = "Rotationally resolved, laser-induced fluorescence spectra for the transitions nf (3Σg+,3Π g) ←a 3Σu+ (n = 4-6) in Ne2 are presented and analyzed. The rotational structures of the upper states are found to be strongly l-uncoupled. Effective rotational constants for the a 3Σu+, nfσ 3Σu+, and nfπ 3 u± states with n = 4-6 are reported and the structures of the nf complexes discussed.",

author = "Kim, {S. B.} and Kane, {D. J.} and Eden, {J. G.} and Ginter, {Marshall L.}",

year = "1991",

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AU - Eden, J. G.

AU - Ginter, Marshall L.

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N2 - Rotationally resolved, laser-induced fluorescence spectra for the transitions nf (3Σg+,3Π g) ←a 3Σu+ (n = 4-6) in Ne2 are presented and analyzed. The rotational structures of the upper states are found to be strongly l-uncoupled. Effective rotational constants for the a 3Σu+, nfσ 3Σu+, and nfπ 3 u± states with n = 4-6 are reported and the structures of the nf complexes discussed.

AB - Rotationally resolved, laser-induced fluorescence spectra for the transitions nf (3Σg+,3Π g) ←a 3Σu+ (n = 4-6) in Ne2 are presented and analyzed. The rotational structures of the upper states are found to be strongly l-uncoupled. Effective rotational constants for the a 3Σu+, nfσ 3Σu+, and nfπ 3 u± states with n = 4-6 are reported and the structures of the nf complexes discussed.

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