Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates

Keyphrases

• FeFe-hydrogenase 100%
• Bridging Hydride 66%
• Low Temperature 33%
• Catalytic Cycle 33%
• Density Functional Calculations 33%
• High Efficiency 33%
• Two-electron 33%
• IR Spectroscopy 33%
• Proton-coupled Electron Transfer 33%
• Chlamydomonas Reinhardtii 33%
• Strongly Reversible 33%
• Nuclear Resonance Vibrational Spectroscopy 33%
• Converting Enzyme 33%
• Desulfovibrio Desulfuricans 33%

Chemistry

• Hydrogenase 100%
• Nuclear Resonance 33%
• vibrational spectroscopy 33%
• Density Functional Theory 33%
• Electron Transport 33%
• catalytic cycle 33%
• IR spectroscopy 33%

Biochemistry, Genetics and Molecular Biology

• Hydrogenase 100%
• Enzyme 66%
• Electron Transport 33%
• Chlamydomonas reinhardtii 33%
• Desulfovibrio desulfuricans 33%