Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO₂ and H⁺ reduction

Keyphrases

• Reaction Mechanism 100%
• Spectroelectrochemical Method 100%
• Electrocatalytic 100%
• Cyclam 100%
• Nickel Cyclam 100%
• CO2 Reduction Reaction (CO2RR) 28%
• Proton 14%
• Working Electrode 14%
• Large Surface Area 14%
• Density Functional Calculations 14%
• H2PO4- 14%
• Spectroscopic Analysis 14%
• Catalytic Properties 14%
• Reducing Conditions 14%
• Resonance Raman 14%
• Mechanistic Information 14%
• Mechanistic Investigation 14%
• Single Species 14%
• Activity Assay 14%
• Glassy Carbon 14%
• Tetraazacyclotetradecane 14%
• Optical Resonance 14%
• Useful Products 14%
• Electrochemical Analysis 14%
• Amorphous Graphite 14%
• N2 Gas 14%
• Differential Reactivity 14%
• Atmospheric Carbon Dioxide 14%
• Catalytic Intermediates 14%
• CO2 Gas 14%
• Carbon Graphite 14%
• Gas Shows 14%
• Molecular Catalyst 14%
• CO Gas 14%
• Molecular Factors 14%
• Graphite Rod 14%
• Oxidizing Potential 14%
• Selective CO2 Reduction 14%

Chemistry

• Carbon Dioxide 100%
• Carbon Dioxide Reduction 100%
• Buffer Solution 33%
• EPR Spectroscopy 33%
• Working Electrode 33%
• Density Functional Theory 33%
• Surface Area 33%
• Spectroscopic Analysis 33%
• Carbon Dioxide 33%
• Catalyst Property 33%
• Electro Analytical Method 33%
• 1,4,8,11-tetraazacyclotetradecane 33%

Biochemistry, Genetics and Molecular Biology

• Optics 100%
• Surface Area 100%